Ring-opening polymerization of 19-electron [2]cobaltocenophanes: a route to high-molecular-weight, water-soluble polycobaltocenium polyelectrolytes.
Water-soluble, high-molecular-weight polycobaltocenium polyelectrolytes have been prepared by ring-opening polymerization (ROP) techniques. Anionic polymerization of a strained 19-electron dicarba[2]cobaltocenophane followed by oxidation in the presence of ammonium chloride resulted in the formation...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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2009
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| _version_ | 1797072722855985152 |
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| author | Mayer, U Gilroy, J O'Hare, D Manners, I |
| author_facet | Mayer, U Gilroy, J O'Hare, D Manners, I |
| author_sort | Mayer, U |
| collection | OXFORD |
| description | Water-soluble, high-molecular-weight polycobaltocenium polyelectrolytes have been prepared by ring-opening polymerization (ROP) techniques. Anionic polymerization of a strained 19-electron dicarba[2]cobaltocenophane followed by oxidation in the presence of ammonium chloride resulted in the formation of oligomers with up to nine repeat units. Thermal ROP of dicarba[2]cobaltocenophane followed by oxidation in the presence of ammonium nitrate resulted in the formation of high-molecular-weight polycobaltocenium nitrate, a redox-active cobalt-containing polyelectrolyte. |
| first_indexed | 2024-03-06T23:11:46Z |
| format | Journal article |
| id | oxford-uuid:65b83f6c-37df-4580-9c1c-628b6b47fba7 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:11:46Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:65b83f6c-37df-4580-9c1c-628b6b47fba72022-03-26T18:27:16ZRing-opening polymerization of 19-electron [2]cobaltocenophanes: a route to high-molecular-weight, water-soluble polycobaltocenium polyelectrolytes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:65b83f6c-37df-4580-9c1c-628b6b47fba7EnglishSymplectic Elements at Oxford2009Mayer, UGilroy, JO'Hare, DManners, IWater-soluble, high-molecular-weight polycobaltocenium polyelectrolytes have been prepared by ring-opening polymerization (ROP) techniques. Anionic polymerization of a strained 19-electron dicarba[2]cobaltocenophane followed by oxidation in the presence of ammonium chloride resulted in the formation of oligomers with up to nine repeat units. Thermal ROP of dicarba[2]cobaltocenophane followed by oxidation in the presence of ammonium nitrate resulted in the formation of high-molecular-weight polycobaltocenium nitrate, a redox-active cobalt-containing polyelectrolyte. |
| spellingShingle | Mayer, U Gilroy, J O'Hare, D Manners, I Ring-opening polymerization of 19-electron [2]cobaltocenophanes: a route to high-molecular-weight, water-soluble polycobaltocenium polyelectrolytes. |
| title | Ring-opening polymerization of 19-electron [2]cobaltocenophanes: a route to high-molecular-weight, water-soluble polycobaltocenium polyelectrolytes. |
| title_full | Ring-opening polymerization of 19-electron [2]cobaltocenophanes: a route to high-molecular-weight, water-soluble polycobaltocenium polyelectrolytes. |
| title_fullStr | Ring-opening polymerization of 19-electron [2]cobaltocenophanes: a route to high-molecular-weight, water-soluble polycobaltocenium polyelectrolytes. |
| title_full_unstemmed | Ring-opening polymerization of 19-electron [2]cobaltocenophanes: a route to high-molecular-weight, water-soluble polycobaltocenium polyelectrolytes. |
| title_short | Ring-opening polymerization of 19-electron [2]cobaltocenophanes: a route to high-molecular-weight, water-soluble polycobaltocenium polyelectrolytes. |
| title_sort | ring opening polymerization of 19 electron 2 cobaltocenophanes a route to high molecular weight water soluble polycobaltocenium polyelectrolytes |
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