Enantioselective rhodium-catalysed insertion of trifluorodiazoethanes into tin hydrides
Aryl substituted 2,2,2-trifluorodiazoethanes undergo rhodium(II)-catalysed insertion reactions with tin hydrides affording the corresponding α-(trifluoromethyl)benzyl stannanes. This reactivity contrasts with that of diazo esters which predominantly afford CH2 reduction products in the presence of t...
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Bibliographic Details
| Main Authors: |
Hyde, S,
Veliks, J,
Ascough, D,
Szpera, R,
Paton, R,
Gouverneur, V |
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| Format: | Journal article
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| Language: | English |
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| Published: |
Elsevier
2018
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