Enantioselective rhodium-catalysed insertion of trifluorodiazoethanes into tin hydrides

Enantioselective rhodium-catalysed insertion of trifluorodiazoethanes into tin hydrides

Aryl substituted 2,2,2-trifluorodiazoethanes undergo rhodium(II)-catalysed insertion reactions with tin hydrides affording the corresponding α-(trifluoromethyl)benzyl stannanes. This reactivity contrasts with that of diazo esters which predominantly afford CH2 reduction products in the presence of t...

पूर्ण विवरण

ग्रंथसूची विवरण
मुख्य लेखकों:	Hyde, S, Veliks, J, Ascough, D, Szpera, R, Paton, R, Gouverneur, V
स्वरूप:	Journal article
भाषा:	English
प्रकाशित:	Elsevier 2018

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