Enantioselective rhodium-catalysed insertion of trifluorodiazoethanes into tin hydrides
Aryl substituted 2,2,2-trifluorodiazoethanes undergo rhodium(II)-catalysed insertion reactions with tin hydrides affording the corresponding α-(trifluoromethyl)benzyl stannanes. This reactivity contrasts with that of diazo esters which predominantly afford CH2 reduction products in the presence of t...
Asıl Yazarlar: | Hyde, S, Veliks, J, Ascough, D, Szpera, R, Paton, R, Gouverneur, V |
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Materyal Türü: | Journal article |
Dil: | English |
Baskı/Yayın Bilgisi: |
Elsevier
2018
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