Enantioselective rhodium-catalysed insertion of trifluorodiazoethanes into tin hydrides

Enantioselective rhodium-catalysed insertion of trifluorodiazoethanes into tin hydrides

Aryl substituted 2,2,2-trifluorodiazoethanes undergo rhodium(II)-catalysed insertion reactions with tin hydrides affording the corresponding α-(trifluoromethyl)benzyl stannanes. This reactivity contrasts with that of diazo esters which predominantly afford CH2 reduction products in the presence of t...

书目详细资料
Main Authors:	Hyde, S, Veliks, J, Ascough, D, Szpera, R, Paton, R, Gouverneur, V
格式:	Journal article
语言:	English
出版:	Elsevier 2018

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