Probing the structures of gas-phase rhodium cluster cations by far-infrared spectroscopy.
The geometric structures of small cationic rhodium clusters Rh(n)(+) (n = 6-12) are investigated by comparison of experimental far-infrared multiple photon dissociation spectra with spectra calculated using density functional theory. The clusters are found to favor structures based on octahedral and...
Main Authors: | Harding, D, Gruene, P, Haertelt, M, Meijer, G, Fielicke, A, Hamilton, S, Hopkins, W, Mackenzie, S, Neville, S, Walsh, T |
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Format: | Journal article |
Jezik: | English |
Izdano: |
AIP Publishing
2010
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