Probing the structures of gas-phase rhodium cluster cations by far-infrared spectroscopy.

The geometric structures of small cationic rhodium clusters Rh(n)(+) (n = 6-12) are investigated by comparison of experimental far-infrared multiple photon dissociation spectra with spectra calculated using density functional theory. The clusters are found to favor structures based on octahedral and...

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Bibliographic Details
Main Authors: Harding, D, Gruene, P, Haertelt, M, Meijer, G, Fielicke, A, Hamilton, S, Hopkins, W, Mackenzie, S, Neville, S, Walsh, T
Format: Journal article
Language:English
Published: AIP Publishing 2010