Crossed-beam and reduced dimensionality studies of the state-to-state integral cross sections of the Cl + HCD3(v) → HCl(v′) + CD3 reaction
The state-to-state integral cross sections of the Cl + HCD3(v) → HCl(v′) + CD3 reaction have been studied experimentally and theoretically. Reactions involving both Cl(2P3/2) and Cl(2P1/2) were analysed. In the experiment, a time-sliced velocity imaging detection method under crossed-beam condition...
| मुख्य लेखकों: | , , , , |
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| स्वरूप: | Journal article |
| भाषा: | English |
| प्रकाशित: |
2013
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| _version_ | 1826276455290503168 |
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| author | Shan, X Remmert, S Clary, D Zhang, B Liu, K |
| author_facet | Shan, X Remmert, S Clary, D Zhang, B Liu, K |
| author_sort | Shan, X |
| collection | OXFORD |
| description | The state-to-state integral cross sections of the Cl + HCD3(v) → HCl(v′) + CD3 reaction have been studied experimentally and theoretically. Reactions involving both Cl(2P3/2) and Cl(2P1/2) were analysed. In the experiment, a time-sliced velocity imaging detection method under crossed-beam condition was used. For theoretical study, a multiple potential energy surface model is employed. A combined reduced dimensionality quantum dynamics and quantum chemistry method is used with explicit treatment of spin-orbit coupling. Good agreement between experiment and theory is obtained, especially for the energy threshold dependence of the cross sections.© 2013 Elsevier B.V. All rights reserved2013 Elsevier B.V. All rights reserved. |
| first_indexed | 2024-03-06T23:14:13Z |
| format | Journal article |
| id | oxford-uuid:668adcd8-b5b1-4fd0-a49b-e2b9cb36a09c |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:14:13Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | oxford-uuid:668adcd8-b5b1-4fd0-a49b-e2b9cb36a09c2022-03-26T18:32:36ZCrossed-beam and reduced dimensionality studies of the state-to-state integral cross sections of the Cl + HCD3(v) → HCl(v′) + CD3 reactionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:668adcd8-b5b1-4fd0-a49b-e2b9cb36a09cEnglishSymplectic Elements at Oxford2013Shan, XRemmert, SClary, DZhang, BLiu, KThe state-to-state integral cross sections of the Cl + HCD3(v) → HCl(v′) + CD3 reaction have been studied experimentally and theoretically. Reactions involving both Cl(2P3/2) and Cl(2P1/2) were analysed. In the experiment, a time-sliced velocity imaging detection method under crossed-beam condition was used. For theoretical study, a multiple potential energy surface model is employed. A combined reduced dimensionality quantum dynamics and quantum chemistry method is used with explicit treatment of spin-orbit coupling. Good agreement between experiment and theory is obtained, especially for the energy threshold dependence of the cross sections.© 2013 Elsevier B.V. All rights reserved2013 Elsevier B.V. All rights reserved. |
| spellingShingle | Shan, X Remmert, S Clary, D Zhang, B Liu, K Crossed-beam and reduced dimensionality studies of the state-to-state integral cross sections of the Cl + HCD3(v) → HCl(v′) + CD3 reaction |
| title | Crossed-beam and reduced dimensionality studies of the state-to-state integral cross sections of the Cl + HCD3(v) → HCl(v′) + CD3 reaction |
| title_full | Crossed-beam and reduced dimensionality studies of the state-to-state integral cross sections of the Cl + HCD3(v) → HCl(v′) + CD3 reaction |
| title_fullStr | Crossed-beam and reduced dimensionality studies of the state-to-state integral cross sections of the Cl + HCD3(v) → HCl(v′) + CD3 reaction |
| title_full_unstemmed | Crossed-beam and reduced dimensionality studies of the state-to-state integral cross sections of the Cl + HCD3(v) → HCl(v′) + CD3 reaction |
| title_short | Crossed-beam and reduced dimensionality studies of the state-to-state integral cross sections of the Cl + HCD3(v) → HCl(v′) + CD3 reaction |
| title_sort | crossed beam and reduced dimensionality studies of the state to state integral cross sections of the cl hcd3 v hcl v cd3 reaction |
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