Rapidly quenched Mg(65)Al(x)CU(25-x)MM(10) (MM : mischmetal) alloys

The ductility of the amorphous Mg-Cu-RE (RE: rare earths) alloys could be improved by means of the partial substitution of Cu atoms by Al ones, as can be interred from the heterogeneous amorphous concept [1,2]. Instead of only one RE element, a solid solution of RE known as mischmetal (MM) was used....

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Main Authors: Audebert, F, Rozenberg, S, Galano, M
Format: Conference item
Published: 2001
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author Audebert, F
Rozenberg, S
Galano, M
author_facet Audebert, F
Rozenberg, S
Galano, M
author_sort Audebert, F
collection OXFORD
description The ductility of the amorphous Mg-Cu-RE (RE: rare earths) alloys could be improved by means of the partial substitution of Cu atoms by Al ones, as can be interred from the heterogeneous amorphous concept [1,2]. Instead of only one RE element, a solid solution of RE known as mischmetal (MM) was used. Rapidly quenched (RQ) samples (cooling rate > 10(3) K s(-1)) of Mg65AlxCu25-xMM10 (0 less than or equal to x less than or equal to 25 at.%) alloys were obtained in a splat cooling device. The structure and the crystallisation process were observed by means of X-ray diffraction (XRD) and differential scanning calorimetry (DSC). Fractographic analysis was carried out by scanning electron microscopy (SEM) on the fracture surface of samples broken by hand bending. With increase of the Al concentration, we observed that both the glass forming ability (GFA) and the amorphous pre-peak (a-pre-peak) in the XRD pattern decreased; meanwhile the crystallisation temperature increased. On the other hand, the ductility of the 10 at.% Al alloy was improved and a vein pattern was observed in the fracture surfaces. (C) 2001 Elsevier Science B.V. All rights reserved.
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spelling oxford-uuid:66bdc122-7891-4380-9a81-97d72c5ce3892022-03-26T18:33:50ZRapidly quenched Mg(65)Al(x)CU(25-x)MM(10) (MM : mischmetal) alloysConference itemhttp://purl.org/coar/resource_type/c_5794uuid:66bdc122-7891-4380-9a81-97d72c5ce389Symplectic Elements at Oxford2001Audebert, FRozenberg, SGalano, MThe ductility of the amorphous Mg-Cu-RE (RE: rare earths) alloys could be improved by means of the partial substitution of Cu atoms by Al ones, as can be interred from the heterogeneous amorphous concept [1,2]. Instead of only one RE element, a solid solution of RE known as mischmetal (MM) was used. Rapidly quenched (RQ) samples (cooling rate > 10(3) K s(-1)) of Mg65AlxCu25-xMM10 (0 less than or equal to x less than or equal to 25 at.%) alloys were obtained in a splat cooling device. The structure and the crystallisation process were observed by means of X-ray diffraction (XRD) and differential scanning calorimetry (DSC). Fractographic analysis was carried out by scanning electron microscopy (SEM) on the fracture surface of samples broken by hand bending. With increase of the Al concentration, we observed that both the glass forming ability (GFA) and the amorphous pre-peak (a-pre-peak) in the XRD pattern decreased; meanwhile the crystallisation temperature increased. On the other hand, the ductility of the 10 at.% Al alloy was improved and a vein pattern was observed in the fracture surfaces. (C) 2001 Elsevier Science B.V. All rights reserved.
spellingShingle Audebert, F
Rozenberg, S
Galano, M
Rapidly quenched Mg(65)Al(x)CU(25-x)MM(10) (MM : mischmetal) alloys
title Rapidly quenched Mg(65)Al(x)CU(25-x)MM(10) (MM : mischmetal) alloys
title_full Rapidly quenched Mg(65)Al(x)CU(25-x)MM(10) (MM : mischmetal) alloys
title_fullStr Rapidly quenched Mg(65)Al(x)CU(25-x)MM(10) (MM : mischmetal) alloys
title_full_unstemmed Rapidly quenched Mg(65)Al(x)CU(25-x)MM(10) (MM : mischmetal) alloys
title_short Rapidly quenched Mg(65)Al(x)CU(25-x)MM(10) (MM : mischmetal) alloys
title_sort rapidly quenched mg 65 al x cu 25 x mm 10 mm mischmetal alloys
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AT rozenbergs rapidlyquenchedmg65alxcu25xmm10mmmischmetalalloys
AT galanom rapidlyquenchedmg65alxcu25xmm10mmmischmetalalloys