Voltammetry at spatially heterogeneous electrodes
Recent advances are overviewed which enable simulation of the voltammetric behaviour of surfaces which respond in an electrochemically spatially heterogeneous fashion. By use of the concept of a "diffusion domain" computationally expensive three-dimensional simulations may be reduced to tr...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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2005
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| _version_ | 1826276498962644992 |
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| author | Davies, T Banks, C Compton, R |
| author_facet | Davies, T Banks, C Compton, R |
| author_sort | Davies, T |
| collection | OXFORD |
| description | Recent advances are overviewed which enable simulation of the voltammetric behaviour of surfaces which respond in an electrochemically spatially heterogeneous fashion. By use of the concept of a "diffusion domain" computationally expensive three-dimensional simulations may be reduced to tractable two-dimensional equivalents. In this way the electrochemical response of partially blocked electrodes and microelectrode arrays may be predicted, and are found to be consistent with experimental data. It is, furthermore, possible to adapt the "blocked" electrode analysis to enable the voltammetric sizing of inert particles present on an electrode surface. Finally theory of this type predicts the voltammetric behaviour of electrochemically heterogeneous electrodes-for example composites whose different spatial zones display contrasting electrochemical behaviour toward the same redox couple. © Springer-Verlag 2005. |
| first_indexed | 2024-03-06T23:14:52Z |
| format | Journal article |
| id | oxford-uuid:66c8fe4c-bd4d-4c04-955d-5b8cd35d7d02 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:14:52Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | oxford-uuid:66c8fe4c-bd4d-4c04-955d-5b8cd35d7d022022-03-26T18:34:04ZVoltammetry at spatially heterogeneous electrodesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:66c8fe4c-bd4d-4c04-955d-5b8cd35d7d02EnglishSymplectic Elements at Oxford2005Davies, TBanks, CCompton, RRecent advances are overviewed which enable simulation of the voltammetric behaviour of surfaces which respond in an electrochemically spatially heterogeneous fashion. By use of the concept of a "diffusion domain" computationally expensive three-dimensional simulations may be reduced to tractable two-dimensional equivalents. In this way the electrochemical response of partially blocked electrodes and microelectrode arrays may be predicted, and are found to be consistent with experimental data. It is, furthermore, possible to adapt the "blocked" electrode analysis to enable the voltammetric sizing of inert particles present on an electrode surface. Finally theory of this type predicts the voltammetric behaviour of electrochemically heterogeneous electrodes-for example composites whose different spatial zones display contrasting electrochemical behaviour toward the same redox couple. © Springer-Verlag 2005. |
| spellingShingle | Davies, T Banks, C Compton, R Voltammetry at spatially heterogeneous electrodes |
| title | Voltammetry at spatially heterogeneous electrodes |
| title_full | Voltammetry at spatially heterogeneous electrodes |
| title_fullStr | Voltammetry at spatially heterogeneous electrodes |
| title_full_unstemmed | Voltammetry at spatially heterogeneous electrodes |
| title_short | Voltammetry at spatially heterogeneous electrodes |
| title_sort | voltammetry at spatially heterogeneous electrodes |
| work_keys_str_mv | AT daviest voltammetryatspatiallyheterogeneouselectrodes AT banksc voltammetryatspatiallyheterogeneouselectrodes AT comptonr voltammetryatspatiallyheterogeneouselectrodes |