Group 12 Metal Complexes of N-Heterocyclic Ditopic Carbanionic Carbenes

Reaction of the N-heterocyclic carbene 1,3-bis(2,6-diisopropylphenyl) imidazol-2-ylidene (IPr) with M(mes)2 (M = Zn, Cd) in diethyl ether afforded the Lewis acid-base adducts [M(IPr)(mes)2] (M = Zn (1), Cd (2)) in quantitative yields. An analogous reaction between Hg(mes)2 and IPr failed to form the...

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Bibliographic Details
Main Authors: Waters, J, Turbervill, R, Goicoechea, J
Format: Journal article
Language:English
Published: 2013