Bonding in pentalene complexes and their recent applications

Bonding in pentalene complexes and their recent applications

Molecular orbital (MO) theory is used to describe the bonding in transition metal pentalene complexes in a variety of its coordination modes. The various MO models account for structural parameters and lead to simple rules for electron counting in pentalene complexes. Recent applications of pentalen...

Descrizione completa

Dettagli Bibliografici
Autori principali:	Cloke, F, Green, J, Kilpatrick, A, O'Hare, D
Natura:	Journal article
Pubblicazione:	Elsevier 2016

Documenti analoghi

Bonding in complexes of bis(pentalene)dititanium, Ti2(C8H6)2
di: Kilpatrick, A, et al.
Pubblicazione: (2015)

Reactivity of a dititanium bis(pentalene) complex toward heteroallenes and main-group element–element bonds
di: Kilpatrick, A, et al.
Pubblicazione: (2016)

Pentalene complexes of chromium, manganese and rhenium.
di: Jones, S, et al.
Pubblicazione: (2002)

A novel coordination mode for pentalene in trinuclear chromium complexes.
di: Jones, S, et al.
Pubblicazione: (2003)

Complexes of iron(II) with silylated pentalene ligands; building blocks for homo- and heterobimetallics
di: Kilpatrick, AFR, et al.
Pubblicazione: (2016)

Bis(pentalene)dititanium chemistry: C–H, C–X and H–H bond activation
di: Tsoureas, N, et al.
Pubblicazione: (2018)

Single-molecule magnet properties of a monometallic dysprosium pentalene complex
di: Kilpatrick, AFR, et al.
Pubblicazione: (2018)

Convenient solution route to alkylated pentalene ligands: New metal monoalkylpentalenyl complexes
di: Jones, S, et al.
Pubblicazione: (2006)

The hexamethylpentalene dianion and other reagents for organometallic pentalene chemistry.
di: Ashley, A, et al.
Pubblicazione: (2007)

[V(eta5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms.
di: Jones, S, et al.
Pubblicazione: (2003)

Pentalene complexes of group 7 metal carbonyls: an organometallic mixed-valence system with very large metal-metal electronic coupling.
di: Jones, S, et al.
Pubblicazione: (2002)

Cerium(III) and cerium(IV) bis(eta(8)-pentalene) sandwich complexes: Synthetic, structural, spectroscopic, and theoretical studies
di: Balazs, G, et al.
Pubblicazione: (2007)

A Dichromium(II) BiS(eta(8)-pentalene) double-sandwich complex with a spin equilibrium: Synthetic, structural, magnetic, and theoretical studies
di: Balazs, G, et al.
Pubblicazione: (2008)

Zirconium arene triple-decker sandwich complexes: synthesis, electronic structure and bonding
di: Kilpatrick, A, et al.
Pubblicazione: (2017)

New Pathways to Precursors of Pentalene
di: Shaochun You, et al.
Pubblicazione: (1996-01-01)

Bonding in bis(pentalene)dimolybdenum: Density functional calculations on Mo-2(C8H6)(2) and photoelectron spectroscopy of Mo-2(C8H4(1,4-SiPr3i)(2))(2)
di: Cloke, F, et al.
Pubblicazione: (1999)

The reductive activation of CO2 across a Ti═Ti double bond: synthetic, structural, and mechanistic studies
di: Kilpatrick, A, et al.
Pubblicazione: (2015)

ACTIVATION OF SP3 CARBON-HYDROGEN BONDS OF ALKYLBENZENES BY RHENIUM FORMING BINUCLEAR MU-ARYLIDENE DERIVATIVES
di: Cloke, F, et al.
Pubblicazione: (1983)

Synthetic, structural, and bonding studies of indacene dianions
di: Cary, DR, et al.
Pubblicazione: (1997)

Synthetic, structural, and bonding studies of indacene dianions
di: Cary, DR, et al.
Pubblicazione: (1997)

syn-Permethylpentalene iron and cobalt carbonyl complexes: Proximity bimetallics lacking metal-metal bonding
di: Ashley, A, et al.
Pubblicazione: (2007)

syn-Permethylpentalene iron and cobalt carbonyl complexes: Proximity bimetallics lacking metal-metal bonding
di: Ashley, A, et al.
Pubblicazione: (2007)

The first example of the two‐electron reduction of a phosphaalkyne – synthesis and structural characterisation of the diuranium(IV) pentalene complex [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3‐1,4)2})2(μ‐η2:η1‐tBuCP)]
di: Tsoureas, N, et al.
Pubblicazione: (2013)

Synthesis, Structure, and Bonding for Bis(permethylpentalene)diiron
di: Myers, W, et al.
Pubblicazione: (2015)

Intercalation chemistry of layered double hydroxides: recent developments and applications
di: Khan, A, et al.
Pubblicazione: (2002)

5,10-Diiododibenzo[<i>a</i>,<i>e</i>]pentalene
di: Natsumi Ohara, et al.
Pubblicazione: (2024-12-01)

The Effect of Benzannulation on the Structures, Reactivity and Molecular Dynamics of Indenes, Pentalenes, Azulenes and Related Molecules
di: Michael J. McGlinchey
Pubblicazione: (2022-06-01)

SYNTHESIS OF HETERO-BINUCLEAR DERIVATIVES OF THE TETRATHIOLATO COMPLEXES [MO(ETA-C5H4CH2CH2SR)2(SR)2)], R=PRN AND PH, WITH PLATINUM, PALLADIUM, AND RHODIUM
di: Ohare, D, et al.
Pubblicazione: (1985)

Recent advances in the synthesis and application of layered double hydroxide (LDH) nanosheets.
di: Wang, Q, et al.
Pubblicazione: (2012)

ON THE STABILITY AND BONDING IN BIS(ETA-ARENE)LANTHANIDE COMPLEXES
di: Anderson, D, et al.
Pubblicazione: (1989)

Zirconium permethylpentalene amidinate complexes: characterization, bonding, and olefin polymerization catalysis
di: Robinson, TP, et al.
Pubblicazione: (2022)

Electronic structure and structural distortions in MCp(R)Tp complexes.
di: O'Hare, D, et al.
Pubblicazione: (2002)

Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers
di: Bruno de la Torre, et al.
Pubblicazione: (2020-09-01)

Electronic structures of mixed-sandwich complexes of cyclopentadienyl and Hydrotris(pyrazolyl)borate ligands with 3d transition metals.
di: Brunker, T, et al.
Pubblicazione: (2003)

CrCpTp: a high-spin Cr(II) sandwich complex with a large structural distortion.
di: Brunker, T, et al.
Pubblicazione: (2002)

CrCpTp: a high-spin Cr(II) sandwich complex with a large structural distortion.
di: Brunker, T, et al.
Pubblicazione: (2002)

THE ACTIVATION OF CARBON-HYDROGEN BONDS
di: Green, M, et al.
Pubblicazione: (1985)

CO₂ activation by permethylpentalene amido zirconium complexes
di: Hamilton, EA, et al.
Pubblicazione: (2021)

SYNTHESIS AND STRUCTURE OF THE 1ST ETA(6)-PYRAZINE COMPLEX [V(ETA(6)-ME4PYRAZINE)(2)] AND RELATED STUDIES
di: Mcghee, W, et al.
Pubblicazione: (1993)

ACTIVATION OF CARBON-HYDROGEN BONDS BY METAL ATOMS
di: Green, M, et al.
Pubblicazione: (1987)