Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
A new functional-group tolerant, rhodium-catalyzed, sulfide-reduction process is combined with rhodium-catalyzed chelation-controlled hydroacylation reactions to give a traceless hydroacylation protocol. Aryl- and alkenyl aldehydes can be combined with both alkenes, alkynes and allenes to give trace...
| 主要な著者: | , , , |
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| フォーマット: | Journal article |
| 言語: | English |
| 出版事項: |
2013
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| _version_ | 1826276718532362240 |
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| author | Hooper, J Young, R Weller, A Willis, M |
| author_facet | Hooper, J Young, R Weller, A Willis, M |
| author_sort | Hooper, J |
| collection | OXFORD |
| description | A new functional-group tolerant, rhodium-catalyzed, sulfide-reduction process is combined with rhodium-catalyzed chelation-controlled hydroacylation reactions to give a traceless hydroacylation protocol. Aryl- and alkenyl aldehydes can be combined with both alkenes, alkynes and allenes to give traceless products in high yields. A preliminary mechanistic proposal is also presented. |
| first_indexed | 2024-03-06T23:18:06Z |
| format | Journal article |
| id | oxford-uuid:67d0fa1c-e854-423c-8b8f-850c8d2c461e |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:18:06Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | oxford-uuid:67d0fa1c-e854-423c-8b8f-850c8d2c461e2022-03-26T18:40:50ZTraceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:67d0fa1c-e854-423c-8b8f-850c8d2c461eEnglishSymplectic Elements at Oxford2013Hooper, JYoung, RWeller, AWillis, MA new functional-group tolerant, rhodium-catalyzed, sulfide-reduction process is combined with rhodium-catalyzed chelation-controlled hydroacylation reactions to give a traceless hydroacylation protocol. Aryl- and alkenyl aldehydes can be combined with both alkenes, alkynes and allenes to give traceless products in high yields. A preliminary mechanistic proposal is also presented. |
| spellingShingle | Hooper, J Young, R Weller, A Willis, M Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation. |
| title | Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation. |
| title_full | Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation. |
| title_fullStr | Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation. |
| title_full_unstemmed | Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation. |
| title_short | Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation. |
| title_sort | traceless chelation controlled rhodium catalyzed intermolecular alkene and alkyne hydroacylation |
| work_keys_str_mv | AT hooperj tracelesschelationcontrolledrhodiumcatalyzedintermolecularalkeneandalkynehydroacylation AT youngr tracelesschelationcontrolledrhodiumcatalyzedintermolecularalkeneandalkynehydroacylation AT wellera tracelesschelationcontrolledrhodiumcatalyzedintermolecularalkeneandalkynehydroacylation AT willism tracelesschelationcontrolledrhodiumcatalyzedintermolecularalkeneandalkynehydroacylation |