Gold(I)-catalyzed intermolecular hydroalkoxylation of allenes: a DFT study.

Gold(I)-catalyzed intermolecular hydroalkoxylation of allenes: a DFT study.

The mechanistic and regiochemical aspects in the Au(I)-catalyzed intermolecular hydroalkoxylation of allenes have been studied computationally. The most favorable pathway is nucleophilic attack of an Au(I)-coordinated allene, which occurs irreversibly. An Au(I)-catalyzed mechanism is proposed that a...

Mô tả đầy đủ

Chi tiết về thư mục
Những tác giả chính:	Paton, R, Maseras, F
Định dạng:	Journal article
Ngôn ngữ:	English
Được phát hành:	2009

Những quyển sách tương tự

Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides
Bằng: Chen Zhang, et al.
Được phát hành: (2013-05-01)

Gold-Catalyzed Hydroalkoxylation/Povarov Reaction Cascade of Alkynols with N‑Aryl Imines: Synthesis of Tetrahydroquinolines
Bằng: Ciwang He, et al.
Được phát hành: (2019-09-01)

Cobalt-catalyzed intermolecular [2+2] cycloaddition between alkynes and allenes
Bằng: Ding, Wei, et al.
Được phát hành: (2020)

Anti-Addition Mechanism in the Intramolecular Hydroalkoxylation of Alkenes Catalyzed by PVP-Stabilized Nanogold
Bằng: Hidehiro Sakurai, et al.
Được phát hành: (2012-03-01)

Small gold nanoparticles for tandem cyclization/reduction and cyclization/hydroalkoxylation reactions
Bằng: Kristína Plevová, et al.
Được phát hành: (2024-10-01)

Intermolecular rhodium catalyzed hydroacylation of allenes: the regioselective synthesis of beta,gamma-unsaturated ketones
Bằng: Randell-Sly, H, et al.
Được phát hành: (2009)

Indium(III)‐catalyzed hydration and hydroalkoxylation of α,β‐unsaturated ketones in aqueous media
Bằng: Yun, Jin-Jin, et al.
Được phát hành: (2020)

Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes.
Bằng: Osborne, J, et al.
Được phát hành: (2008)

Rhodium (I) catalyzed intermolecular hydroacylation.
Bằng: Sapmaz, S, et al.
Được phát hành: (2001)

Gold(I)-Catalyzed 1,6-Enyne Single-Cleavage Rearrangements: The Complete Picture
Bằng: Eduardo García-Padilla, et al.
Được phát hành: (2023-08-01)

Expedient syntheses of N-heterocycles via intermolecular amphoteric diamination of allenes
Bằng: Zhishi Ye, et al.
Được phát hành: (2018-02-01)

Gold(I)-catalyzed intramolecular cyclization/intermolecular cycloaddition cascade as a fast track to polycarbocycles and mechanistic insights
Bằng: Cheng Zhang, et al.
Được phát hành: (2021-02-01)

Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
Bằng: Yali Zhou, et al.
Được phát hành: (2021-03-01)

Gold-Catalyzed Complementary Nitroalkyne Internal Redox Process: A DFT Study
Bằng: K. Vipin Raj, et al.
Được phát hành: (2021-07-01)

Access to quinolines through gold-catalyzed intermolecular cycloaddition of 2-aminoaryl carbonyls and internal alkynes
Bằng: Cai, Shuting, et al.
Được phát hành: (2013)

Chemoselectivity in Gold(I)-Catalyzed Propargyl Ester Reactions: Insights From DFT Calculations
Bằng: Qing Sun, et al.
Được phát hành: (2019-09-01)

Rhodium-catalyzed enantioselective intermolecular hydroacylation reactions
Bằng: Gonzalez-Rodriguez, C, et al.
Được phát hành: (2011)

Nickel-catalyzed acylzincation of allenes with organozincs and CO
Bằng: Xianqing Wu, et al.
Được phát hành: (2023-10-01)

An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation
Bằng: Straker, R, et al.
Được phát hành: (2018)

Palladium-catalyzed intermolecular heck-type reaction of epoxides
Bằng: Teng, Shenghan, et al.
Được phát hành: (2020)

Synthesis of Polysubstituted Tetrahydropyrans by Stereoselective Hydroalkoxylation of Silyl Alkenols: En Route to Tetrahydropyranyl Marine Analogues
Bằng: Carlos Díez-Poza, et al.
Được phát hành: (2018-11-01)

Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangement
Bằng: Bo Zhou, et al.
Được phát hành: (2019-07-01)

DFT Study on the Mechanism of Iron-Catalyzed Diazocarbonylation
Bằng: Tímea R. Kégl, et al.
Được phát hành: (2020-12-01)

Synthesis of [1,4]Oxathiepino[5,6-b]quinolines via Base-Mediated Intramolecular Hydroalkoxylation
Bằng: Maryam-Sadat Tonekaboni, et al.
Được phát hành: (2022-01-01)

Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
Bằng: Hooper, J, et al.
Được phát hành: (2013)

Cobalt-catalyzed hydroacylative dimerization of allenes leading to skipped dienes
Bằng: Ding, Wei, et al.
Được phát hành: (2020)

Copper(I)-catalyzed diastereo- and enantio-selective construction of optically pure exocyclic allenes
Bằng: Cheng-Yu He, et al.
Được phát hành: (2020-08-01)

The Azide-Allene Dipolar Cycloaddition: Is DFT Able to Predict Site- and Regio-Selectivity?
Bằng: Giorgio Molteni, et al.
Được phát hành: (2021-02-01)

Intermolecular Forces Driving Hexamethylenetetramine Co-Crystal Formation, a DFT and XRD Analysis
Bằng: Giovanni Bella, et al.
Được phát hành: (2021-09-01)

Copper-catalyzed intermolecular Regio- and Enantioselective Hydrosilylation of Alkenes with Prochiral Silanes
Bằng: Xiao-Yan Zhu, et al.
Được phát hành: (2025-01-01)

Supported Palladium Nanoparticles Catalyzed Intermolecular Carbopalladation of Nitriles and Organoboron Compounds
Bằng: Xin Liu, et al.
Được phát hành: (2022-05-01)

Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation
Bằng: Honggui Lv, et al.
Được phát hành: (2019-11-01)

Synthetic scope and DFT analysis of the chiral binap–gold(I) complex-catalyzed 1,3-dipolar cycloaddition of azlactones with alkenes
Bằng: María Martín-Rodríguez, et al.
Được phát hành: (2013-11-01)

Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes
Bằng: Liu, Richard Y., et al.
Được phát hành: (2018)

a-Amidoaldehydes as substrates in rhodium-catalyzed intermolecular alkyne hydroacylation: The synthesis of a-amidoketones
Bằng: Pal, R, et al.
Được phát hành: (2020)

Intermolecular Non-Covalent Carbon-Bonding Interactions with Methyl Groups: A CSD, PDB and DFT Study
Bằng: Tiddo J. Mooibroek
Được phát hành: (2019-09-01)

Chiral phosphoric acid-catalyzed stereodivergent synthesis of trisubstituted allenes and computational mechanistic studies
Bằng: Jiawen Wang, et al.
Được phát hành: (2020-11-01)

A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes
Bằng: Tsai, Erica Y., et al.
Được phát hành: (2020)

A Study of Palladium Catalyzed Intra/Intermolecular Cascade Cross Coupling/Cyclizations Involving Bicyclopropylidene
Bằng: Aydin Demircan
Được phát hành: (2014-05-01)

α‐Amidoaldehydes as substrates in rhodium‐catalyzed intermolecular alkyne hydroacylation: The synthesis of α‐Amidoketones
Bằng: Pal, R, et al.
Được phát hành: (2020)