Voltammetric demonstration of thermally induced natural convection in aqueous solution

In electrochemical systems imperfect thermostating inevitably leads to the presence of bulk convective flows. As recognised by Nernst [Z. Phys. Chem., 1904, 52] damping of these bulk convective flows next to a solid surface, or at the electrode, leads to diffusional mass transport predominating loca...

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Bibliographic Details
Main Authors: Li, D, Batchelor-Mcauley, C, Chen, L, Compton, R
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2019