Stable formally zerovalent and diamagnetic monovalent niobium and tantalum complexes based on diazadiene ligands.
This paper describes the efficient synthesis and full characterization of rare formally zerovalent and diamagnetic monovalent pseudooctahedral niobium and tantalum complexes. The reaction of NbCl(4)(thf)(2) with 4 equiv of Na and 3.5 equiv of iPr(2)-dad (1,4-diisopropyl-1,4-diaza-1,3-diene) yields N...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2002
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