$Probing molten salt flux reactions using time-resolved in situ high-temperature powder X-ray diffraction: A new synthesis route to the mixed-valence NaTi2O4$

Probing molten salt flux reactions using time-resolved in situ high-temperature powder X-ray diffraction: A new synthesis route to the mixed-valence NaTi2O4

A new molten salt synthesis route to the mixed-valence sodium titanate NaTi2O4 has been discovered. Reduction of Na 8Ti5O14 by Ti metal powder in a 3:1 molar mixture of NaCl:KCl at 770 °C produced crystals of NaTi2O 4. Use of the molten salt flux lowered the synthesis temperature of this compound by...

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Bibliographic Details
Main Authors:	Geselbracht, M, Noailles, L, Ngo, LT, Pikul, J, Walton, R, Cowell, E, Millange, F, O'Hare, D
Format:	Journal article
Language:	English
Published:	2004

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Crystallization of a Large-Pore Three-Dimensional Gallium Fluorophosphate under Mild Conditions This work was supported by EPSRC and the Novartis Trust Fund. The EPSRC provided access to Daresbury Laboratory. We are grateful to L. M. D. Cranswick of Daresbury Laboratory for valuable discussions, Dr. S. O'Leary (Oxford) for performing the thermogravimetric analysis (TGA) measurements, and Professor K. Kuroda (Waseda University) for performing the gas adsorption measurements. The authors acknowledge the EPSRC-funded Collaborative Computational Project Number 14 (http://www.ccp14.ac.uk) for software resources applied in data analysis.
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