Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V^4+, x = 0; M = Ga^3+, x = 1): co-existence of ordered and disordered quantum spins in the V^4+ system.
The title compounds are bimetallic MOFs containing [Cu(pyz)2]^2+ square lattices linked by MF6^n- octahedra. In each, only the Cu^2+ spins exhibit long-range magnetic order below 3.5 K (M = V^4+) and 2.6 K (M = Ga^3+). The V^4+ spins remain disordered down to 0.5 K.
Бібліографічні деталі
| Автори: |
Manson, J,
Schlueter, J,
Garrett, K,
Goddard, P,
Lancaster, T,
Möller, J,
Blundell, S,
Steele, A,
Franke, I,
Pratt, F,
Singleton, J,
Bendix, J,
Lapidus, S,
Uhlarz, M,
Ayala-Valenzuela, O,
McDonald, R,
Gurak, M,
Baines, C |
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| Формат: | Journal article
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| Мова: | English |
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| Опубліковано: |
Royal Society of Chemistry
2016
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