Electrolyte induced electrical dis-connection between single graphene nanoplatelets and an electrode

We report the influence of electrolyte on the electrical contact between graphene nanoplates (GNPs) and an electrode via a single entity electrochemical technique. The current 'steps' were observed in the absence of electrolyte due to the GNPs impacting on and bridging across an interdigit...

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Main Authors: Krittayavathananon, A, Li, X, Batchelor-Mcauley, C, Sawangphruk, M, Compton, R
Format: Journal article
Jezik:English
Izdano: American Chemical Society 2018
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author Krittayavathananon, A
Li, X
Batchelor-Mcauley, C
Sawangphruk, M
Compton, R
author_facet Krittayavathananon, A
Li, X
Batchelor-Mcauley, C
Sawangphruk, M
Compton, R
author_sort Krittayavathananon, A
collection OXFORD
description We report the influence of electrolyte on the electrical contact between graphene nanoplates (GNPs) and an electrode via a single entity electrochemical technique. The current 'steps' were observed in the absence of electrolyte due to the GNPs impacting on and bridging across an interdigitated gold electrode array (IDE), in contrast current spikes of short duration were obtained in the presence of electrolyte. This result indicates that in the latter case the constant short circuit bridging current was switched off and replaced solely by impacts of GNPs with single electrodes. These observed current spikes measured in the presence of electrolyte are evidenced to be of a capacitative nature, demonstrating the high sensitivity of the electronic properties of the GNPs/metal junction to the ionic strength of the electrolytic solution.
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spelling oxford-uuid:6921cde9-d2e4-49e5-a5b9-72e42f58aa822022-03-26T18:49:26ZElectrolyte induced electrical dis-connection between single graphene nanoplatelets and an electrodeJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:6921cde9-d2e4-49e5-a5b9-72e42f58aa82EnglishSymplectic Elements at OxfordAmerican Chemical Society2018Krittayavathananon, ALi, XBatchelor-Mcauley, CSawangphruk, MCompton, RWe report the influence of electrolyte on the electrical contact between graphene nanoplates (GNPs) and an electrode via a single entity electrochemical technique. The current 'steps' were observed in the absence of electrolyte due to the GNPs impacting on and bridging across an interdigitated gold electrode array (IDE), in contrast current spikes of short duration were obtained in the presence of electrolyte. This result indicates that in the latter case the constant short circuit bridging current was switched off and replaced solely by impacts of GNPs with single electrodes. These observed current spikes measured in the presence of electrolyte are evidenced to be of a capacitative nature, demonstrating the high sensitivity of the electronic properties of the GNPs/metal junction to the ionic strength of the electrolytic solution.
spellingShingle Krittayavathananon, A
Li, X
Batchelor-Mcauley, C
Sawangphruk, M
Compton, R
Electrolyte induced electrical dis-connection between single graphene nanoplatelets and an electrode
title Electrolyte induced electrical dis-connection between single graphene nanoplatelets and an electrode
title_full Electrolyte induced electrical dis-connection between single graphene nanoplatelets and an electrode
title_fullStr Electrolyte induced electrical dis-connection between single graphene nanoplatelets and an electrode
title_full_unstemmed Electrolyte induced electrical dis-connection between single graphene nanoplatelets and an electrode
title_short Electrolyte induced electrical dis-connection between single graphene nanoplatelets and an electrode
title_sort electrolyte induced electrical dis connection between single graphene nanoplatelets and an electrode
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AT batchelormcauleyc electrolyteinducedelectricaldisconnectionbetweensinglegraphenenanoplateletsandanelectrode
AT sawangphrukm electrolyteinducedelectricaldisconnectionbetweensinglegraphenenanoplateletsandanelectrode
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