Structural anomalies at the magnetic transition in centrosymmetric BiMnO$_3$

The structural properties of BiMn$O_3$ were determined from neutron powder diffraction data as a function of temperature and magnetic field. The structure at all temperatures was found to be centrosymmetric with space group $C2/c$, which is incompatible with ferroelectricity. At T$_C\simeq 100 K$, w...

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Autores principales: Montanari, E, Calestani, G, Righi, L, Gilioli, E, Bolzoni, F, Knight, K, Radaelli, P
Formato: Journal article
Lenguaje:English
Publicado: 2007
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author Montanari, E
Calestani, G
Righi, L
Gilioli, E
Bolzoni, F
Knight, K
Radaelli, P
author_facet Montanari, E
Calestani, G
Righi, L
Gilioli, E
Bolzoni, F
Knight, K
Radaelli, P
author_sort Montanari, E
collection OXFORD
description The structural properties of BiMn$O_3$ were determined from neutron powder diffraction data as a function of temperature and magnetic field. The structure at all temperatures was found to be centrosymmetric with space group $C2/c$, which is incompatible with ferroelectricity. At T$_C\simeq 100 K$, we observed the onset of a large magnetoelastic strain, proportional to the square of the magnetization. We interpret this structural rearrangement, together with the previously observed magnetodielectric anomalies, as due to the need to optimize the partially frustrated magnetic interactions.
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spelling oxford-uuid:6936c33d-b55c-40ab-9783-c3e71acb19e92022-03-26T18:49:55ZStructural anomalies at the magnetic transition in centrosymmetric BiMnO$_3$Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:6936c33d-b55c-40ab-9783-c3e71acb19e9EnglishSymplectic Elements at Oxford2007Montanari, ECalestani, GRighi, LGilioli, EBolzoni, FKnight, KRadaelli, PThe structural properties of BiMn$O_3$ were determined from neutron powder diffraction data as a function of temperature and magnetic field. The structure at all temperatures was found to be centrosymmetric with space group $C2/c$, which is incompatible with ferroelectricity. At T$_C\simeq 100 K$, we observed the onset of a large magnetoelastic strain, proportional to the square of the magnetization. We interpret this structural rearrangement, together with the previously observed magnetodielectric anomalies, as due to the need to optimize the partially frustrated magnetic interactions.
spellingShingle Montanari, E
Calestani, G
Righi, L
Gilioli, E
Bolzoni, F
Knight, K
Radaelli, P
Structural anomalies at the magnetic transition in centrosymmetric BiMnO$_3$
title Structural anomalies at the magnetic transition in centrosymmetric BiMnO$_3$
title_full Structural anomalies at the magnetic transition in centrosymmetric BiMnO$_3$
title_fullStr Structural anomalies at the magnetic transition in centrosymmetric BiMnO$_3$
title_full_unstemmed Structural anomalies at the magnetic transition in centrosymmetric BiMnO$_3$
title_short Structural anomalies at the magnetic transition in centrosymmetric BiMnO$_3$
title_sort structural anomalies at the magnetic transition in centrosymmetric bimno 3
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