The charge transfer kinetics of the oxidation of silver and nickel nanoparticles via particle-electrode impact electrochemistry.
The electro-oxidation of silver and nickel nanoparticles in aqueous solution was studied via their collisions with a carbon electrode. The average charge passed per impact varies with electrode potential and was analysed to determine that AgNPs display an electrochemically fast ("reversible&quo...
| Main Authors: | , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2012
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| 总结: | The electro-oxidation of silver and nickel nanoparticles in aqueous solution was studied via their collisions with a carbon electrode. The average charge passed per impact varies with electrode potential and was analysed to determine that AgNPs display an electrochemically fast ("reversible") one-electron oxidation, whilst the NiNPs exhibit slow ("irreversible") 2-electron kinetics. Kinetic parameters are reported. |
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