Synthesis and structure of organometallic derivatives of 1,2,3,4,5,6,7,8-octamethyl-1,5-dihydro-s-indacene
A new fused-ring compound 1,2,3,4,5,6,7,8-octamethyl-1,5-dihydro-s-indacene (H 2L 1) has been synthesized from p-xylene. Three transition-metal derivatives [Mn(η 5-HL 1)(CO) 3], [Rh(η 5-HL 1)(η-C 5Me 5)] +[SbF 6] - and [Cr(η 6-H 2L 1)(CO) 3] have been characterised: spectroscopic and crystallographi...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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1997
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| _version_ | 1797073641034219520 |
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| author | Barlow, S Cary, DR Drewitt, M OHare, D |
| author_facet | Barlow, S Cary, DR Drewitt, M OHare, D |
| author_sort | Barlow, S |
| collection | OXFORD |
| description | A new fused-ring compound 1,2,3,4,5,6,7,8-octamethyl-1,5-dihydro-s-indacene (H 2L 1) has been synthesized from p-xylene. Three transition-metal derivatives [Mn(η 5-HL 1)(CO) 3], [Rh(η 5-HL 1)(η-C 5Me 5)] +[SbF 6] - and [Cr(η 6-H 2L 1)(CO) 3] have been characterised: spectroscopic and crystallographic data for these compounds show the ligand system is strongly electron donating. Although H 2L 1 is readily deprotonated to the monoanion by potassium metal or potassium hydride, surprisingly we have been unable to form (L 1) 2-. The crystal structure of [K] +[HL 1] -·19-crown-6 reveals the potassium ion to be sandwiched between the crown ether (1,4,7,10,13,16-hexaoxacyclooctadecane) and the (HL 1) - anion. |
| first_indexed | 2024-03-06T23:24:57Z |
| format | Journal article |
| id | oxford-uuid:6a097f06-5a1a-4a8a-a39a-19aa886a7363 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:24:57Z |
| publishDate | 1997 |
| record_format | dspace |
| spelling | oxford-uuid:6a097f06-5a1a-4a8a-a39a-19aa886a73632022-03-26T18:54:55ZSynthesis and structure of organometallic derivatives of 1,2,3,4,5,6,7,8-octamethyl-1,5-dihydro-s-indaceneJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:6a097f06-5a1a-4a8a-a39a-19aa886a7363EnglishSymplectic Elements at Oxford1997Barlow, SCary, DRDrewitt, MOHare, DA new fused-ring compound 1,2,3,4,5,6,7,8-octamethyl-1,5-dihydro-s-indacene (H 2L 1) has been synthesized from p-xylene. Three transition-metal derivatives [Mn(η 5-HL 1)(CO) 3], [Rh(η 5-HL 1)(η-C 5Me 5)] +[SbF 6] - and [Cr(η 6-H 2L 1)(CO) 3] have been characterised: spectroscopic and crystallographic data for these compounds show the ligand system is strongly electron donating. Although H 2L 1 is readily deprotonated to the monoanion by potassium metal or potassium hydride, surprisingly we have been unable to form (L 1) 2-. The crystal structure of [K] +[HL 1] -·19-crown-6 reveals the potassium ion to be sandwiched between the crown ether (1,4,7,10,13,16-hexaoxacyclooctadecane) and the (HL 1) - anion. |
| spellingShingle | Barlow, S Cary, DR Drewitt, M OHare, D Synthesis and structure of organometallic derivatives of 1,2,3,4,5,6,7,8-octamethyl-1,5-dihydro-s-indacene |
| title | Synthesis and structure of organometallic derivatives of 1,2,3,4,5,6,7,8-octamethyl-1,5-dihydro-s-indacene |
| title_full | Synthesis and structure of organometallic derivatives of 1,2,3,4,5,6,7,8-octamethyl-1,5-dihydro-s-indacene |
| title_fullStr | Synthesis and structure of organometallic derivatives of 1,2,3,4,5,6,7,8-octamethyl-1,5-dihydro-s-indacene |
| title_full_unstemmed | Synthesis and structure of organometallic derivatives of 1,2,3,4,5,6,7,8-octamethyl-1,5-dihydro-s-indacene |
| title_short | Synthesis and structure of organometallic derivatives of 1,2,3,4,5,6,7,8-octamethyl-1,5-dihydro-s-indacene |
| title_sort | synthesis and structure of organometallic derivatives of 1 2 3 4 5 6 7 8 octamethyl 1 5 dihydro s indacene |
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