Bifunctional iminophosphorane superbases: Potent organocatalysts for enantio- and diastereoselective Michael addition reactions

Bifunctional iminophosphorane (BIMP) organocatalysts catalyze the enantio- and diastereoselective Michael additions of high pKacyclic malonamate ester pro-nucleophiles to nitroalkenes with reactivity profiles of up to 3 orders of magnitude greater than tertiary amine bifunctional Brønsted base/(thio...

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Bibliografische gegevens
Hoofdauteurs: Farley, A, Jakubec, P, Goldys, A, Dixon, D
Formaat: Journal article
Gepubliceerd in: Elsevier 2018