Expedient construction of the [7-5-5] all-carbon tricyclic core of the Daphniphyllum alkaloids daphnilongeranin B and daphniyunnine D.
A synthetic strategy for the construction of the [7-5-5] all-carbon tricyclic core of numerous calyciphylline A-type Daphniphyllum alkaloids has been developed using a key intramolecular Pauson-Khand reaction. A subsequent base-mediated double-bond migration and a regio- and stereoselective radical...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
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2012
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| _version_ | 1797073856297435136 |
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| author | Darses, B Michaelides, I Sladojevich, F Ward, J Rzepa, P Dixon, D |
| author_facet | Darses, B Michaelides, I Sladojevich, F Ward, J Rzepa, P Dixon, D |
| author_sort | Darses, B |
| collection | OXFORD |
| description | A synthetic strategy for the construction of the [7-5-5] all-carbon tricyclic core of numerous calyciphylline A-type Daphniphyllum alkaloids has been developed using a key intramolecular Pauson-Khand reaction. A subsequent base-mediated double-bond migration and a regio- and stereoselective radical late stage allylic oxygenation provide access to the substitution patterns of daphnilongeranin B and daphniyunnine D. |
| first_indexed | 2024-03-06T23:27:56Z |
| format | Journal article |
| id | oxford-uuid:6b095d92-ee7e-4bcc-8631-5d4a1958a3e3 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:27:56Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | oxford-uuid:6b095d92-ee7e-4bcc-8631-5d4a1958a3e32022-03-26T19:01:09ZExpedient construction of the [7-5-5] all-carbon tricyclic core of the Daphniphyllum alkaloids daphnilongeranin B and daphniyunnine D.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:6b095d92-ee7e-4bcc-8631-5d4a1958a3e3EnglishSymplectic Elements at Oxford2012Darses, BMichaelides, ISladojevich, FWard, JRzepa, PDixon, DA synthetic strategy for the construction of the [7-5-5] all-carbon tricyclic core of numerous calyciphylline A-type Daphniphyllum alkaloids has been developed using a key intramolecular Pauson-Khand reaction. A subsequent base-mediated double-bond migration and a regio- and stereoselective radical late stage allylic oxygenation provide access to the substitution patterns of daphnilongeranin B and daphniyunnine D. |
| spellingShingle | Darses, B Michaelides, I Sladojevich, F Ward, J Rzepa, P Dixon, D Expedient construction of the [7-5-5] all-carbon tricyclic core of the Daphniphyllum alkaloids daphnilongeranin B and daphniyunnine D. |
| title | Expedient construction of the [7-5-5] all-carbon tricyclic core of the Daphniphyllum alkaloids daphnilongeranin B and daphniyunnine D. |
| title_full | Expedient construction of the [7-5-5] all-carbon tricyclic core of the Daphniphyllum alkaloids daphnilongeranin B and daphniyunnine D. |
| title_fullStr | Expedient construction of the [7-5-5] all-carbon tricyclic core of the Daphniphyllum alkaloids daphnilongeranin B and daphniyunnine D. |
| title_full_unstemmed | Expedient construction of the [7-5-5] all-carbon tricyclic core of the Daphniphyllum alkaloids daphnilongeranin B and daphniyunnine D. |
| title_short | Expedient construction of the [7-5-5] all-carbon tricyclic core of the Daphniphyllum alkaloids daphnilongeranin B and daphniyunnine D. |
| title_sort | expedient construction of the 7 5 5 all carbon tricyclic core of the daphniphyllum alkaloids daphnilongeranin b and daphniyunnine d |
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