Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics
The theory of "two-dimensional voltammetry" using arrays of gold channel microband electrodes ranging in size from the millimeter to the micrometer scale is extended to permit the deduction of electrochemical rate constants through the analysis of hydrodynamic voltammograms as a function o...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1999
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| _version_ | 1826277475454287872 |
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| author | Prieto, F Alden, J Feldman, M Coles, B Compton, R Oyama, M Okazaki, S |
| author_facet | Prieto, F Alden, J Feldman, M Coles, B Compton, R Oyama, M Okazaki, S |
| author_sort | Prieto, F |
| collection | OXFORD |
| description | The theory of "two-dimensional voltammetry" using arrays of gold channel microband electrodes ranging in size from the millimeter to the micrometer scale is extended to permit the deduction of electrochemical rate constants through the analysis of hydrodynamic voltammograms as a function of both electrode size and electrolyte flow rate (convection). The technique is applied to the reduction of p-chloranil and the oxidation of 2,3,7,8-tetramethoxythianthrene both in acetonitrile solution and electrochemical rate constants are reported. |
| first_indexed | 2024-03-06T23:29:27Z |
| format | Journal article |
| id | oxford-uuid:6b825d69-9093-4d72-be07-d8c7983b5618 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:29:27Z |
| publishDate | 1999 |
| record_format | dspace |
| spelling | oxford-uuid:6b825d69-9093-4d72-be07-d8c7983b56182022-03-26T19:04:35ZChannel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kineticsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:6b825d69-9093-4d72-be07-d8c7983b5618EnglishSymplectic Elements at Oxford1999Prieto, FAlden, JFeldman, MColes, BCompton, ROyama, MOkazaki, SThe theory of "two-dimensional voltammetry" using arrays of gold channel microband electrodes ranging in size from the millimeter to the micrometer scale is extended to permit the deduction of electrochemical rate constants through the analysis of hydrodynamic voltammograms as a function of both electrode size and electrolyte flow rate (convection). The technique is applied to the reduction of p-chloranil and the oxidation of 2,3,7,8-tetramethoxythianthrene both in acetonitrile solution and electrochemical rate constants are reported. |
| spellingShingle | Prieto, F Alden, J Feldman, M Coles, B Compton, R Oyama, M Okazaki, S Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics |
| title | Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics |
| title_full | Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics |
| title_fullStr | Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics |
| title_full_unstemmed | Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics |
| title_short | Channel microband electrode arrays for mechanistic electrochemistry. Two-dimensional voltammetry: Electrode kinetics |
| title_sort | channel microband electrode arrays for mechanistic electrochemistry two dimensional voltammetry electrode kinetics |
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