Recent Developments in the Use of Layered Double Hydroxides as Host Materials for the Storage and Triggered Release of Functional Anions
An extensive and systematic study of the intercalation of a number of commercially important anions into a range of layered double hydroxides (LDHs) has been undertaken. A pseudo-combinatorial approach was employed to determine rapidly the ideal reaction conditions for the intercalation of each gues...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2009
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| _version_ | 1797073966602387456 |
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| author | Khan, A Ragavan, A Fong, B Markland, C O'Brien, M Dunbar, T Williams, G O'Hare, D |
| author_facet | Khan, A Ragavan, A Fong, B Markland, C O'Brien, M Dunbar, T Williams, G O'Hare, D |
| author_sort | Khan, A |
| collection | OXFORD |
| description | An extensive and systematic study of the intercalation of a number of commercially important anions into a range of layered double hydroxides (LDHs) has been undertaken. A pseudo-combinatorial approach was employed to determine rapidly the ideal reaction conditions for the intercalation of each guest. Over 50 LDH nanohybrids are reported, the vast majority of them having never previously been synthesized. Guest anions include key drugs, important agrochemicals, vitamins, fragrances, a dye, and a color fixant. The immense potential of LDH systems as reservoirs and to remove agrochemical pollutants from effluvium flows was demonstrated. The release of the guest anions was studied in representative conditions. Some of the thiosulfate intercalates show temperature programmable release characteristics which have not be observed previously. © 2009 American Chemical Society. |
| first_indexed | 2024-03-06T23:29:30Z |
| format | Journal article |
| id | oxford-uuid:6b881cb2-c8a6-4585-aad7-ae0dbd60db9e |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:29:30Z |
| publishDate | 2009 |
| record_format | dspace |
| spelling | oxford-uuid:6b881cb2-c8a6-4585-aad7-ae0dbd60db9e2022-03-26T19:04:42ZRecent Developments in the Use of Layered Double Hydroxides as Host Materials for the Storage and Triggered Release of Functional AnionsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:6b881cb2-c8a6-4585-aad7-ae0dbd60db9eEnglishSymplectic Elements at Oxford2009Khan, ARagavan, AFong, BMarkland, CO'Brien, MDunbar, TWilliams, GO'Hare, DAn extensive and systematic study of the intercalation of a number of commercially important anions into a range of layered double hydroxides (LDHs) has been undertaken. A pseudo-combinatorial approach was employed to determine rapidly the ideal reaction conditions for the intercalation of each guest. Over 50 LDH nanohybrids are reported, the vast majority of them having never previously been synthesized. Guest anions include key drugs, important agrochemicals, vitamins, fragrances, a dye, and a color fixant. The immense potential of LDH systems as reservoirs and to remove agrochemical pollutants from effluvium flows was demonstrated. The release of the guest anions was studied in representative conditions. Some of the thiosulfate intercalates show temperature programmable release characteristics which have not be observed previously. © 2009 American Chemical Society. |
| spellingShingle | Khan, A Ragavan, A Fong, B Markland, C O'Brien, M Dunbar, T Williams, G O'Hare, D Recent Developments in the Use of Layered Double Hydroxides as Host Materials for the Storage and Triggered Release of Functional Anions |
| title | Recent Developments in the Use of Layered Double Hydroxides as Host Materials for the Storage and Triggered Release of Functional Anions |
| title_full | Recent Developments in the Use of Layered Double Hydroxides as Host Materials for the Storage and Triggered Release of Functional Anions |
| title_fullStr | Recent Developments in the Use of Layered Double Hydroxides as Host Materials for the Storage and Triggered Release of Functional Anions |
| title_full_unstemmed | Recent Developments in the Use of Layered Double Hydroxides as Host Materials for the Storage and Triggered Release of Functional Anions |
| title_short | Recent Developments in the Use of Layered Double Hydroxides as Host Materials for the Storage and Triggered Release of Functional Anions |
| title_sort | recent developments in the use of layered double hydroxides as host materials for the storage and triggered release of functional anions |
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