Electro-chemo-mechanical phase field modeling of localized corrosion: theory and COMSOL implementation
A new theoretical phase field-based formulation for predicting electro-chemo-mechanical corrosion in metals is presented. The model combines electrolyte and interface electrochemical behaviour with a phase field description of mechanically-assisted corrosion accounting for film rupture, dissolution...
| Main Authors: | , , |
|---|---|
| Format: | Journal article |
| Jezik: | English |
| Izdano: |
Springer
2023
|
| _version_ | 1826312449720057856 |
|---|---|
| author | Cui, C Ma, R Martínez-Pañeda, E |
| author_facet | Cui, C Ma, R Martínez-Pañeda, E |
| author_sort | Cui, C |
| collection | OXFORD |
| description | A new theoretical phase field-based formulation for predicting electro-chemo-mechanical corrosion in metals is presented. The model combines electrolyte and interface electrochemical behaviour with a phase field description of mechanically-assisted corrosion accounting for film rupture, dissolution and repassivation. The theoretical framework is numerically implemented in the finite element package COMSOL MULTIPHYSICS and the resulting model is made freely available. Several numerical experiments are conducted showing that the corrosion predictions by the model naturally capture the influence of varying electrostatic potential and electrolyte concentrations, as well as predicting the sensitivity to the pit geometry and the strength of the passivation film. |
| first_indexed | 2024-03-07T08:29:09Z |
| format | Journal article |
| id | oxford-uuid:6c83c0aa-dc2f-4f89-9e17-b0f807e02258 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T08:29:09Z |
| publishDate | 2023 |
| publisher | Springer |
| record_format | dspace |
| spelling | oxford-uuid:6c83c0aa-dc2f-4f89-9e17-b0f807e022582024-02-29T17:58:00ZElectro-chemo-mechanical phase field modeling of localized corrosion: theory and COMSOL implementationJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:6c83c0aa-dc2f-4f89-9e17-b0f807e02258EnglishSymplectic ElementsSpringer2023Cui, CMa, RMartínez-Pañeda, EA new theoretical phase field-based formulation for predicting electro-chemo-mechanical corrosion in metals is presented. The model combines electrolyte and interface electrochemical behaviour with a phase field description of mechanically-assisted corrosion accounting for film rupture, dissolution and repassivation. The theoretical framework is numerically implemented in the finite element package COMSOL MULTIPHYSICS and the resulting model is made freely available. Several numerical experiments are conducted showing that the corrosion predictions by the model naturally capture the influence of varying electrostatic potential and electrolyte concentrations, as well as predicting the sensitivity to the pit geometry and the strength of the passivation film. |
| spellingShingle | Cui, C Ma, R Martínez-Pañeda, E Electro-chemo-mechanical phase field modeling of localized corrosion: theory and COMSOL implementation |
| title | Electro-chemo-mechanical phase field modeling of localized corrosion: theory and COMSOL implementation |
| title_full | Electro-chemo-mechanical phase field modeling of localized corrosion: theory and COMSOL implementation |
| title_fullStr | Electro-chemo-mechanical phase field modeling of localized corrosion: theory and COMSOL implementation |
| title_full_unstemmed | Electro-chemo-mechanical phase field modeling of localized corrosion: theory and COMSOL implementation |
| title_short | Electro-chemo-mechanical phase field modeling of localized corrosion: theory and COMSOL implementation |
| title_sort | electro chemo mechanical phase field modeling of localized corrosion theory and comsol implementation |
| work_keys_str_mv | AT cuic electrochemomechanicalphasefieldmodelingoflocalizedcorrosiontheoryandcomsolimplementation AT mar electrochemomechanicalphasefieldmodelingoflocalizedcorrosiontheoryandcomsolimplementation AT martinezpanedae electrochemomechanicalphasefieldmodelingoflocalizedcorrosiontheoryandcomsolimplementation |