Synthesis, crystal structure, and nonlinear optical behavior of beta-unsubstituted meso-meso E-vinylene-linked porphyrin dimers.

Synthesis, crystal structure, and nonlinear optical behavior of beta-unsubstituted meso-meso E-vinylene-linked porphyrin dimers.

[structure: see text] A vinylene-linked porphyrin dimer, with no substituents at the beta-positions, has been synthesized by CuI/CsF promoted Stille coupling. In the crystal structure of this dimer, the C(2)H(2) bridge is twisted by 45 degrees relative to the plane of the porphyrins. The absorption,...

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Bibliografiska uppgifter
Huvudupphovsmän: Frampton, M, Akdas, H, Cowley, A, Rogers, J, Slagle, J, Fleitz, P, Drobizhev, M, Rebane, A, Anderson, H
Materialtyp: Journal article
Språk:English
Publicerad: 2005

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