Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity.
The pathway for the combination of enones and beta-S-substituted aldehydes using Rh-catalysis can be switched between a hydroacylation reaction or a reductive aldol reaction by simple choice of the phosphine ligand; this catalyst controlled switch allows access to new ketone hydroacylation products;...
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| Autori principali: |
Osborne, J,
Willis, M |
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| Natura: | Journal article
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| Lingua: | English |
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| Pubblicazione: |
2008
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