Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity.
The pathway for the combination of enones and beta-S-substituted aldehydes using Rh-catalysis can be switched between a hydroacylation reaction or a reductive aldol reaction by simple choice of the phosphine ligand; this catalyst controlled switch allows access to new ketone hydroacylation products;...
| मुख्य लेखकों: | , |
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| स्वरूप: | Journal article |
| भाषा: | English |
| प्रकाशित: |
2008
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| _version_ | 1826277865403973632 |
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| author | Osborne, J Willis, M |
| author_facet | Osborne, J Willis, M |
| author_sort | Osborne, J |
| collection | OXFORD |
| description | The pathway for the combination of enones and beta-S-substituted aldehydes using Rh-catalysis can be switched between a hydroacylation reaction or a reductive aldol reaction by simple choice of the phosphine ligand; this catalyst controlled switch allows access to new ketone hydroacylation products; useful 1,4-diketone intermediates for the synthesis of N-, S- and O-heterocycles. |
| first_indexed | 2024-03-06T23:35:20Z |
| format | Journal article |
| id | oxford-uuid:6d7722c9-6ac0-4f43-a6ba-ca66c783678d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:35:20Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:6d7722c9-6ac0-4f43-a6ba-ca66c783678d2022-03-26T19:17:57ZRhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:6d7722c9-6ac0-4f43-a6ba-ca66c783678dEnglishSymplectic Elements at Oxford2008Osborne, JWillis, MThe pathway for the combination of enones and beta-S-substituted aldehydes using Rh-catalysis can be switched between a hydroacylation reaction or a reductive aldol reaction by simple choice of the phosphine ligand; this catalyst controlled switch allows access to new ketone hydroacylation products; useful 1,4-diketone intermediates for the synthesis of N-, S- and O-heterocycles. |
| spellingShingle | Osborne, J Willis, M Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity. |
| title | Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity. |
| title_full | Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity. |
| title_fullStr | Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity. |
| title_full_unstemmed | Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity. |
| title_short | Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity. |
| title_sort | rhodium catalysed hydroacylation or reductive aldol reactions a ligand dependent switch of reactivity |
| work_keys_str_mv | AT osbornej rhodiumcatalysedhydroacylationorreductivealdolreactionsaliganddependentswitchofreactivity AT willism rhodiumcatalysedhydroacylationorreductivealdolreactionsaliganddependentswitchofreactivity |