Direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalyst.
It is shown that for molecules of Allochromatium vinosum [NiFe]-hydrogenase adsorbed on a pyrolytic graphite electrode the nickel-iron active site catalyzes hydrogen oxidation at a diffusion-controlled rate matching that achieved by platinum.
| Main Authors: | , , , |
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| Format: | Journal article |
| Published: |
2002
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| _version_ | 1797074474134142976 |
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| author | Jones, A Sillery, E Albracht, S Armstrong, F |
| author_facet | Jones, A Sillery, E Albracht, S Armstrong, F |
| author_sort | Jones, A |
| collection | OXFORD |
| description | It is shown that for molecules of Allochromatium vinosum [NiFe]-hydrogenase adsorbed on a pyrolytic graphite electrode the nickel-iron active site catalyzes hydrogen oxidation at a diffusion-controlled rate matching that achieved by platinum. |
| first_indexed | 2024-03-06T23:36:42Z |
| format | Journal article |
| id | oxford-uuid:6de7f7a0-1144-4cc5-a1a1-c1dcc2d7c444 |
| institution | University of Oxford |
| last_indexed | 2024-03-06T23:36:42Z |
| publishDate | 2002 |
| record_format | dspace |
| spelling | oxford-uuid:6de7f7a0-1144-4cc5-a1a1-c1dcc2d7c4442022-03-26T19:20:58ZDirect comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalyst.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:6de7f7a0-1144-4cc5-a1a1-c1dcc2d7c444Symplectic Elements at Oxford2002Jones, ASillery, EAlbracht, SArmstrong, FIt is shown that for molecules of Allochromatium vinosum [NiFe]-hydrogenase adsorbed on a pyrolytic graphite electrode the nickel-iron active site catalyzes hydrogen oxidation at a diffusion-controlled rate matching that achieved by platinum. |
| spellingShingle | Jones, A Sillery, E Albracht, S Armstrong, F Direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalyst. |
| title | Direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalyst. |
| title_full | Direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalyst. |
| title_fullStr | Direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalyst. |
| title_full_unstemmed | Direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalyst. |
| title_short | Direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalyst. |
| title_sort | direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalyst |
| work_keys_str_mv | AT jonesa directcomparisonoftheelectrocatalyticoxidationofhydrogenbyanenzymeandaplatinumcatalyst AT sillerye directcomparisonoftheelectrocatalyticoxidationofhydrogenbyanenzymeandaplatinumcatalyst AT albrachts directcomparisonoftheelectrocatalyticoxidationofhydrogenbyanenzymeandaplatinumcatalyst AT armstrongf directcomparisonoftheelectrocatalyticoxidationofhydrogenbyanenzymeandaplatinumcatalyst |