Total synthesis of polycephalin C and determination of the absolute configurations at the 3",4" ring junction.

Total synthesis of polycephalin C and determination of the absolute configurations at the 3",4" ring junction.

Only through total synthesis could the absolute configuration of the 3′′R,4′′R ring junction of the polyenoltetramic acid polycephalin C (1) be unambiguously established. Key features of the synthesis include a double Swern oxidation, double Stille coupling, and a double Takai olefination.

Xehetasun bibliografikoak
Egile Nagusiak:	Longbottom, D, Morrison, A, Dixon, D, Ley, S
Formatua:	Journal article
Hizkuntza:	English
Argitaratua:	2002

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The Total Synthesis of the Annonaceous Acetogenin, Muricatetrocin C We thank the EPSRC (D.J.D. and D.J.R.), the Novartis Research Fellowship (S.V.L.), and the BP Research Endowment (S.V.L.) for generous financial support for this work.
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