Total synthesis of polycephalin C and determination of the absolute configurations at the 3",4" ring junction.

Total synthesis of polycephalin C and determination of the absolute configurations at the 3",4" ring junction.

Only through total synthesis could the absolute configuration of the 3′′R,4′′R ring junction of the polyenoltetramic acid polycephalin C (1) be unambiguously established. Key features of the synthesis include a double Swern oxidation, double Stille coupling, and a double Takai olefination.

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид:	Longbottom, D, Morrison, A, Dixon, D, Ley, S
Формат:	Journal article
Хэл сонгох:	English
Хэвлэсэн:	2002

Ижил төстэй зүйлс

Total synthesis of the polyenoyltetramic acid polycephalin C
-н: Longbottom, D, зэрэг
Хэвлэсэн: (2003)

Total synthesis of the plasmoidal pigment physarorubinic acid, a polyenoyl tetramic acid
-н: Dixon, D, зэрэг
Хэвлэсэн: (1999)

Total Synthesis of Gobiusxanthin Stereoisomers and Their Application to Determination of Absolute Configurations of Natural Products: Revision of Reported Absolute Configuration of Epigobiusxanthin
-н: Yumiko Yamano, зэрэг
Хэвлэсэн: (2014-12-01)

Total Synthesis and Absolute Configuration of the Marine Norditerpenoid Xestenone
-н: Hiroaki Miyaoka, зэрэг
Хэвлэсэн: (2009-11-01)

Synthesis, structure revision, and absolute configuration of (+)-didemniserinolipid B, a serinol marine natural product from a tunicate Didemnum sp.
-н: Kiyota, H, зэрэг
Хэвлэсэн: (2002)

The total synthesis of the annonaceous acetogenin, muricatetrocin C.
-н: Dixon, D, зэрэг
Хэвлэсэн: (2002)

The total synthesis of the annonaceous acetogenin, muricatetrocin C.
-н: Dixon, D, зэрэг
Хэвлэсэн: (2002)

The total synthesis of the annonaceous acetogenin, muricatetrocin C
-н: Dixon, D, зэрэг
Хэвлэсэн: (2002)

(-)-Pseudodistomin E: First asymmetric synthesis and absolute configuration assignment
-н: Davies, S, зэрэг
Хэвлэсэн: (2017)

A highly enantioselective total synthesis of (+)-goniodiol.
-н: Tate, E, зэрэг
Хэвлэсэн: (2006)

Copper(I)-catalyzed preparation of (E)-3-iodoprop-2-enoic acid: (2-Propenoic acid, 3-iodo-, (2E)-)
-н: Dixon, D, зэрэг
Хэвлэсэн: (2003)

Biomimetic synthesis of (-)-Xestospongin A, (+)-Xestospongin C, (+)-Araguspongine B and the correction of their absolute configurations
-н: Baldwin, J, зэрэг
Хэвлэсэн: (1998)

The absolute configuration of curcumalactone /
-н: Gao, Ji-Fu

Absolute configuration of isoeichlerialactone
-н: Hoong-Kun Fun, зэрэг
Хэвлэсэн: (2010-04-01)

Total synthesis of the polyenoyltetramic acid mycotoxin erythroskyrine
-н: Dixon, D, зэрэг
Хэвлэсэн: (1999)

Total synthesis of the Fusarium toxin equisetin.
-н: Burke, LT, зэрэг
Хэвлэсэн: (2005)

Synthesis of an advanced C10-C32 spiroacetal fragment and assignment of the absolute configuration of spirangien A.
-н: Paterson, I, зэрэг
Хэвлэсэн: (2007)

Total synthesis of (-)-nakadomarin A: alkyne ring-closing metathesis
-н: Jakubec, P, зэрэг
Хэвлэсэн: (2011)

Microwave-Assisted Synthesis of (±)-Mandelic Acid-d5, Optical Resolution, and Absolute Configuration Determination
-н: Claudio Bruno, зэрэг
Хэвлэсэн: (2013-01-01)

Synthesis, Chiral Resolution and Enantiomers Absolute Configuration of 4-Nitropropranolol and 7-Nitropropranolol
-н: Rosa Sparaco, зэрэг
Хэвлэсэн: (2022-12-01)

The synthesis of mono- and bicyclic ethers via acid catalysed ring-opening cyclisation of tetrahydropyranyl ether derivatives
-н: Dixon, D, зэрэг
Хэвлэсэн: (2000)

A total synthesis of (+)-Goniodiol using an anomeric oxygen-to-carbon rearrangement
-н: Dixon, D, зэрэг
Хэвлэсэн: (1998)

Chromatographic methods in the determination of absolute and relative configurations of fatty acids /
-н: 451759 Smith, C. R.

Determination of the Absolute Configurations of Chiral Drugs Using Chiroptical Spectroscopy
-н: Prasad L. Polavarapu
Хэвлэсэн: (2016-08-01)

The absolute configuration of 1-epialexine hemihydrate.
-н: Thompson, A, зэрэг
Хэвлэсэн: (2008)

The absolute configuration and conformation of neocurdione /
-н: Tamiko Ohkura

3-Nitroatenolol: First Synthesis, Chiral Resolution and Enantiomers’ Absolute Configuration
-н: Rosa Sparaco, зэрэг
Хэвлэсэн: (2024-04-01)

A short stereoselective total synthesis of the fusarium toxin equisetin.
-н: Burke, LT, зэрэг
Хэвлэсэн: (2000)

Resolution and determination of the absolute configuration of the enantiomers of a trans-α-disulfoxide
-н: Allenmark, Stig, зэрэг
Хэвлэсэн: (2011)

Synthesis of (3S,3′S)- and meso-Stereoisomers of Alloxanthin and Determination of Absolute Configuration of Alloxanthin Isolated from Aquatic Animals
-н: Yumiko Yamano, зэрэг
Хэвлэсэн: (2014-05-01)

The total synthesis of the annonaceous acetogenin 10-hydroxyasimicin.
-н: Nattrass, G, зэрэг
Хэвлэсэн: (2005)

Optically pure trans-1-benzyl-4-aminopiperidin-3-ols. Synthesis and absolute configuration
-н: Galina V. Grishina, зэрэг
Хэвлэсэн: (2011-07-01)

Asymmetric Synthesis and Absolute Configuration Assignment of a New Type of Bedaquiline Analogue
-н: Chang-Jiang Qiao, зэрэг
Хэвлэсэн: (2015-12-01)

Determination of the Absolute Configuration of Aegelinol by Crystallization of Its Inclusion Complex with β-Cyclodextrin
-н: Johan Wouters, зэрэг
Хэвлэсэн: (2012-10-01)

In Silico Modeling of Spirolides and Gymnodimines: Determination of <i>S</i> Configuration at Butenolide Ring Carbon C-4
-н: Christian Zurhelle, зэрэг
Хэвлэсэн: (2020-10-01)

The total synthesis of (+)-aspicilin using 2,3-butane diacetal protected butane tetrols via a chiral memory protocol
-н: Dixon, D, зэрэг
Хэвлэсэн: (2001)

The Total Synthesis of the Annonaceous Acetogenin, Muricatetrocin C We thank the EPSRC (D.J.D. and D.J.R.), the Novartis Research Fellowship (S.V.L.), and the BP Research Endowment (S.V.L.) for generous financial support for this work.
-н: Dixon, D, зэрэг
Хэвлэсэн: (2000)

Levetiracetam analogs: chemoenzymatic synthesis, absolute configuration assignment and evaluation of cholinesterase inhibitory activities
-н: Cintia Duarte de Freitas Milagre, зэрэг
Хэвлэсэн: (2022-04-01)

Levetiracetam analogs: chemoenzymatic synthesis, absolute configuration assignment and evaluation of cholinesterase inhibitory activities
-н: Cintia Duarte de Freitas Milagre, зэрэг
Хэвлэсэн: (2022-04-01)

Atlas of stereochemistry : absolute configurations of organic molecules/
-н: 244867 Klyne, William, зэрэг
Хэвлэсэн: (1978)