Multi-mode absorption spectroscopy for multi-species and multi-parameter sensing
<p>The extension of Multi-mode Absorption Spectroscopy (MUMAS) to the infra-red spectral region for multi-species gas sensing is reported. A computationally efficient, theoretical model for analysis of MUMAS spectra is presented that avoids approximations used in previous work and treats arbit...
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| Format: | Thesis |
| Language: | English |
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2017
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| _version_ | 1797074760200355840 |
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| author | O'Hagan, S |
| author2 | Lucas, D |
| author_facet | Lucas, D O'Hagan, S |
| author_sort | O'Hagan, S |
| collection | OXFORD |
| description | <p>The extension of Multi-mode Absorption Spectroscopy (MUMAS) to the infra-red spectral region for multi-species gas sensing is reported. A computationally efficient, theoretical model for analysis of MUMAS spectra is presented that avoids approximations used in previous work and treats arbitrary and time-dependent spectral intensity envelopes, thus facilitating the use of commercially available Interband Cascade Lasers (ICLs) and Quantum Cascade Lasers (QCLs).</p> <p>The first use of an ICL for MUMAS is reported using a multi-mode device operating at 3.7 μm to detect CH<sub>4</sub> transitions over a range of 30 nm. Mode-linewidths are measured using the pressure-dependent widths of an isolated absorption feature in HCl. Multi- species sensing is demonstrated by measurement of partial pressures of CH<sub>4</sub>, C<sub>2</sub>H<sub>2</sub> and H<sub>2</sub>CO in a low-pressure mixture with uncertainties of around 10%. Detection of CH<sub>4</sub> in N<sub>2</sub> at 1 bar is demonstrated using a shorter-cavity ICL to resolve spectral features in pressure-broadened and congested spectra.</p> <p>The first use of a QCL for MUMAS is reported using a commercially available device operating at 5.3 μm to detect multiple absorption transitions of NO at a partial pressure of 2.79 μbar in N<sub>2</sub> buffer gas. The revised model is shown to enable good fits to MUMAS data by accounting for the time-variation of the spectral intensity profile during frequency scanning. Individual mode-linewidths are derived from fits to pressure- dependent MUMAS spectra and features from background interferences due to H<sub>2</sub>O in laboratory air are distinguished from those of the target species, NO. Data obtained at scan rates up to 10 kHz demonstrate the potential for achieving short measurement times.</p> <p>The development of a balanced ratiometric detection scheme for MUMAS with commercially available multi-mode lasers operating at 1.5 μm is reported for simultaneous detection of CO and CO<sub>2</sub> showing improved SNR performance over previous direct transmission methods and suitability for a compact field-employable instrument. In addition, MUMAS spectra of CO<sub>2</sub> are used to derive gas temperatures with an uncertainty of 3.2% in the range 300 - 700 K.</p> |
| first_indexed | 2024-03-06T23:40:50Z |
| format | Thesis |
| id | oxford-uuid:6f422683-7c50-47dd-8824-56b4b4ea941d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:40:50Z |
| publishDate | 2017 |
| record_format | dspace |
| spelling | oxford-uuid:6f422683-7c50-47dd-8824-56b4b4ea941d2022-03-26T19:29:34ZMulti-mode absorption spectroscopy for multi-species and multi-parameter sensingThesishttp://purl.org/coar/resource_type/c_db06uuid:6f422683-7c50-47dd-8824-56b4b4ea941dPhysicsSpectroscopyLasersMUMASEnglishORA Deposit2017O'Hagan, SLucas, DEwart, PSigrist, M<p>The extension of Multi-mode Absorption Spectroscopy (MUMAS) to the infra-red spectral region for multi-species gas sensing is reported. A computationally efficient, theoretical model for analysis of MUMAS spectra is presented that avoids approximations used in previous work and treats arbitrary and time-dependent spectral intensity envelopes, thus facilitating the use of commercially available Interband Cascade Lasers (ICLs) and Quantum Cascade Lasers (QCLs).</p> <p>The first use of an ICL for MUMAS is reported using a multi-mode device operating at 3.7 μm to detect CH<sub>4</sub> transitions over a range of 30 nm. Mode-linewidths are measured using the pressure-dependent widths of an isolated absorption feature in HCl. Multi- species sensing is demonstrated by measurement of partial pressures of CH<sub>4</sub>, C<sub>2</sub>H<sub>2</sub> and H<sub>2</sub>CO in a low-pressure mixture with uncertainties of around 10%. Detection of CH<sub>4</sub> in N<sub>2</sub> at 1 bar is demonstrated using a shorter-cavity ICL to resolve spectral features in pressure-broadened and congested spectra.</p> <p>The first use of a QCL for MUMAS is reported using a commercially available device operating at 5.3 μm to detect multiple absorption transitions of NO at a partial pressure of 2.79 μbar in N<sub>2</sub> buffer gas. The revised model is shown to enable good fits to MUMAS data by accounting for the time-variation of the spectral intensity profile during frequency scanning. Individual mode-linewidths are derived from fits to pressure- dependent MUMAS spectra and features from background interferences due to H<sub>2</sub>O in laboratory air are distinguished from those of the target species, NO. Data obtained at scan rates up to 10 kHz demonstrate the potential for achieving short measurement times.</p> <p>The development of a balanced ratiometric detection scheme for MUMAS with commercially available multi-mode lasers operating at 1.5 μm is reported for simultaneous detection of CO and CO<sub>2</sub> showing improved SNR performance over previous direct transmission methods and suitability for a compact field-employable instrument. In addition, MUMAS spectra of CO<sub>2</sub> are used to derive gas temperatures with an uncertainty of 3.2% in the range 300 - 700 K.</p> |
| spellingShingle | Physics Spectroscopy Lasers MUMAS O'Hagan, S Multi-mode absorption spectroscopy for multi-species and multi-parameter sensing |
| title | Multi-mode absorption spectroscopy for multi-species and multi-parameter sensing |
| title_full | Multi-mode absorption spectroscopy for multi-species and multi-parameter sensing |
| title_fullStr | Multi-mode absorption spectroscopy for multi-species and multi-parameter sensing |
| title_full_unstemmed | Multi-mode absorption spectroscopy for multi-species and multi-parameter sensing |
| title_short | Multi-mode absorption spectroscopy for multi-species and multi-parameter sensing |
| title_sort | multi mode absorption spectroscopy for multi species and multi parameter sensing |
| topic | Physics Spectroscopy Lasers MUMAS |
| work_keys_str_mv | AT ohagans multimodeabsorptionspectroscopyformultispeciesandmultiparametersensing |