Aqueous-organic biphasic redox-chemistry of high-hydride content rhodium clusters: Towards immobilisation of redox-switchable H-2 binding materials on a surface
Water-insoluble phosphine-surface-stabilised rhodium clusters [Rh6 (PR3)6 H12] [BAr4F]2 (R = cyclohexyl, ArF = (3,5-CF3)2C6H3) can be immobilised onto suitable glassy carbon, graphite, or tin-doped indium oxide (ITO) electrode surfaces. When immersed into alcohol/aqueous electrolyte media, they disp...
| Main Authors: | , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2009
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