Mechanistic insight into benzylidene-directed glycosylation reactions using cryogenic infrared spectroscopy

Mechanistic insight into benzylidene-directed glycosylation reactions using cryogenic infrared spectroscopy

The stereoselective formation of 1,2-cis glycosidic linkages is challenging. The currently most widely used strategy for their installation uses 4,6-O-benzylidene-protected building blocks. The stereoselectivity of this reaction is thought to be driven by a covalent intermediate, which reacts via an...

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Autors principals:	Chang, C, Greis, K, Prabhu, GRD, Wehner, D, Kirschbaum, C, Ober, K, Torres-Boy, AY, Leichnitz, S, Meijer, G, von Helden, G, Seeberger, PH, Pagel, K
Format:	Journal article
Idioma:	English
Publicat:	Nature Research 2024

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