Mechanistic insight into benzylidene-directed glycosylation reactions using cryogenic infrared spectroscopy
The stereoselective formation of 1,2-cis glycosidic linkages is challenging. The currently most widely used strategy for their installation uses 4,6-O-benzylidene-protected building blocks. The stereoselectivity of this reaction is thought to be driven by a covalent intermediate, which reacts via an...
Main Authors: | Chang, C, Greis, K, Prabhu, GRD, Wehner, D, Kirschbaum, C, Ober, K, Torres-Boy, AY, Leichnitz, S, Meijer, G, von Helden, G, Seeberger, PH, Pagel, K |
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格式: | Journal article |
语言: | English |
出版: |
Nature Research
2024
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