Heptamethyl Indenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(III)-catalyzed C-H activation
The diastereoselective coupling of O-substituted arylhydroxamates and cyclopropenes mediated by Rh(III) catalysis was successfully developed. Through ligand development, the diastereoselectivity of this reaction was improved using a heptamethylindenyl (Ind*) ligand, which has been rationalized using...
Main Authors: | Paton, R, Jackson, K, Semakul, N, Rovis, T |
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Format: | Journal article |
Published: |
Royal Society of Chemistry
2016
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