Synthesis, bonding and reactivity of a terminal titanium alkylidene hydrazido compound.

Synthesis, bonding and reactivity of a terminal titanium alkylidene hydrazido compound.

We report a detailed study of the reactions of the Ti=NNCPh2 alkylidene hydrazide functional group in [Cp*Ti{MeC(NiPr)2}(NNCPh2)] (8) with a variety of unsaturated and saturated substrates. Compound 8 was prepared from [Cp*Ti{MeC(NiPr)2}(NtBu)] and Ph2CNNH2. DFT calculations were used to determine t...

Descrizione completa

Dettagli Bibliografici
Autori principali:	Tiong, P, Groom, L, Clot, E, Mountford, P
Natura:	Journal article
Lingua:	English
Pubblicazione:	2013

Documenti analoghi

Synthesis and reactivity of new titanium hydrazido complexes
di: Tiong, P
Pubblicazione: (2012)

New Sandwich and Half-Sandwich Titanium Hydrazido Compounds
di: Selby, J, et al.
Pubblicazione: (2011)

Synthesis and Reactivity of Titanium Hydrazido Complexes Supported by Diamido-Ether Ligands
di: Unruangsri, J, et al.
Pubblicazione: (2013)

Synthesis, structures, and DFT bonding analysis of new titanium hydrazido(2-) complexes.
di: Parsons, T, et al.
Pubblicazione: (2005)

Synthesis and reactivity of titanium hydrazido(2-) complexes
di: Selby, J
Pubblicazione: (2009)

M=N(alpha) cycloaddition and N(alpha)-N(beta) insertion in the reactions of titanium hydrazido compounds with alkynes: a combined experimental and computational study.
di: Schofield, A, et al.
Pubblicazione: (2010)

Synthesis and Reactions of a Cyclopentadienyl-Amidinate Titanium tert-Butoxyimido Compound
di: Groom, L, et al.
Pubblicazione: (2013)

Single and double substrate insertion into the Ti=N(alpha) bonds of terminal titanium hydrazides.
di: Tiong, P, et al.
Pubblicazione: (2010)

Synthesis, structures and reactivity of group 4 hydrazido complexes supported by calix[4]arene ligands.
di: Clulow, A, et al.
Pubblicazione: (2008)

New titanium borylimido compounds: synthesis, structure and bonding
di: Clough, B, et al.
Pubblicazione: (2017)

New reactions of titanium imido and hydrazido complexes
di: Stevenson, L
Pubblicazione: (2015)

Synthesis and reactivity studies of Group 5 imido and hydrazido complexes
di: Gamero-Vega, K
Pubblicazione: (2018)

New scandium borylimido chemistry: synthesis, bonding and reactivity
di: Clough, B, et al.
Pubblicazione: (2017)

Cycloaddition reactions of titanium and zirconium imido, oxo and hydrazido complexes supported by tetraaza macrocyclic ligands
di: Blake, A, et al.
Pubblicazione: (1999)

Si-H and Si-Cl bond activation reactions of titanium hydrazides with silanes and subsequent Ti-H/E-H (E = Si or H) σ-bond metathesis.
di: Tiong, P, et al.
Pubblicazione: (2011)

Titanium tert-butoxyimido compounds.
di: Schwarz, A, et al.
Pubblicazione: (2011)

Synthesis and reactions of titanium-nitrogen multiple bonds
di: Groom, L, et al.
Pubblicazione: (2014)

Synthesis and reactivity of the imidotungsten methyl cation [W(N2Npy)(NPh)Me]+: CO2 adds to the W=NPh bond and does not insert into the W-Me bond.
di: Ward, B, et al.
Pubblicazione: (2002)

Exploring the reactivity of alkylidene malonamides: synthesis of polyfunctionalized isoxazolidinones, aziridines and oxazolines.
di: Alessandra Tolomelli, et al.
Pubblicazione: (2012-05-01)

Synthetic and computational studies of group 3 and group 4 imido and hydrazido compounds
di: Mellino, S
Pubblicazione: (2017)

Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands.
di: Schwarz, A, et al.
Pubblicazione: (2011)

Synthesis of highly substituted allenylsilanes by alkylidenation of silylketenes
di: Stephen P. Marsden, et al.
Pubblicazione: (2005-08-01)

Reactions of Cyclopentadienyl-Amidinate Titanium Hydrazides with CO2, CS2, and Isocyanates: Ti=N-alpha Cycloaddition, Cycloaddition-Insertion, and Cycloaddition-NNR2 Group Transfer Reactions
di: Tiong, P, et al.
Pubblicazione: (2011)

Synthesis and structural characterisation of an yttrium-alkyl-alkylidene.
di: Liddle, S, et al.
Pubblicazione: (2008)

Pendant arm functionalized benzamidinate titanium imido compounds: Experimental and computational studies of their reactions with CO2
di: Boyd, C, et al.
Pubblicazione: (2005)

Reactions of cyclopentadienyl-amidinate titanium imido compounds with CO2: cycloaddition-extrusion vs. cycloaddition-insertion.
di: Guiducci, A, et al.
Pubblicazione: (2009)

Synthesis of Tungsten Oxo Alkylidene Complexes
di: Peryshkov, Dmitry, et al.
Pubblicazione: (2014)

Preparation and reactivity of tantalum(V) alkylidene and metallacyclobutane complexes
di: Wallace, Kevin C. (Kevin Crenshaw)
Pubblicazione: (2010)

Synthesis and Reactivity of a Pentacoordinated Thiolate-Based Imido-Alkylidene W(VI) Complexes
di: Allouche Florian, et al.
Pubblicazione: (2016-03-01)

Synthesis and ethylene polymerization capability of metallocene-like imido titanium dialkyl compounds and their reactions with (AlBu3)-Bu-i
di: Bolton, P, et al.
Pubblicazione: (2006)

Site selectivity and reversibility in the reactions of titanium hydrazides with Si-H, Si-X, C-X and H+ reagents: Ti=N(α) 1,2-silane addition, Nβ alkylation, Nα protonation and σ-bond metathesis.
di: Tiong, P, et al.
Pubblicazione: (2012)

Reactions of titanium imides and hydrazides with boranes
di: Mellino, S, et al.
Pubblicazione: (2017)

Reactions of titanium imides and hydrazides with boranes
di: Mellino, S, et al.
Pubblicazione: (2017)

Synthesis of molybdenum(VI) alkylidene complexes as catalysts for living polymerizations of terminal acetylenes and olefin metathesis
di: Fox, Harold Hamilton
Pubblicazione: (2005)

Synthesis of titanium borylimido compounds supported by diamide-amine ligands and their reactions with alkynes
di: Clough, B, et al.
Pubblicazione: (2018)

Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands
di: Ghodrat Mahmoudi, et al.
Pubblicazione: (2019-06-01)

Synthesis and Biological Evaluation of Novel γ-Alkylidene Butenolides
di: Gai-Zhi Liu, et al.
Pubblicazione: (2013-01-01)

Experimental and DFT studies of cationic imido titanium alkyls: Agostic interactions and C-H bond and solvent activation reactions of isolobal analogues of group 4 metallocenium cations
di: Bolton, P, et al.
Pubblicazione: (2006)

Reactions of a Cyclopentadienyl-Amidinate Titanium Benzimidamido Complex
di: Groom, L, et al.
Pubblicazione: (2014)

Synthesis and reactivity of novel group 4 cyclopentadienyl amidinate imido compounds.
di: Guiducci, A, et al.
Pubblicazione: (2000)