KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL COMPLEXES [FE(CO)(ETA(5)-C5H5)-(L)COCH3] [L=PPH(3), P(P-TOLYL)(3)] VIA ALDOL REACTIONS WITH CAMPHOR
The chiral iron acetyl complexes [Fe(CO)(η5-C 5H5)(L)COCH3] [L = PPh3, P(p-tolyl)3] have been kinetically resolved via aldol reactions involving their derived lithium enolates and camphor in the presence of lithium chloride. With (1R)-(+)-camphor the faster reacting iron acetyl enantiomer had the (S...
| Main Authors: | , , , , , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado: |
1994
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