KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL COMPLEXES [FE(CO)(ETA(5)-C5H5)-(L)COCH3] [L=PPH(3), P(P-TOLYL)(3)] VIA ALDOL REACTIONS WITH CAMPHOR

KINETIC RESOLUTION OF THE CHIRAL IRON ACETYL COMPLEXES [FE(CO)(ETA(5)-C5H5)-(L)COCH3] [L=PPH(3), P(P-TOLYL)(3)] VIA ALDOL REACTIONS WITH CAMPHOR

The chiral iron acetyl complexes [Fe(CO)(η5-C 5H5)(L)COCH3] [L = PPh3, P(p-tolyl)3] have been kinetically resolved via aldol reactions involving their derived lithium enolates and camphor in the presence of lithium chloride. With (1R)-(+)-camphor the faster reacting iron acetyl enantiomer had the (S...

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Bibliographic Details
Main Authors:	Casegreen, S, Costello, J, Davies, S, Heaton, N, Hedgecock, C, Humphreys, V, Metzler, M, Prime, J
Format:	Journal article
Language:	English
Published:	1994

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