Lanthanide complexes of DOTA monoamide derivatives bearing an isophthalate pendent arm.

An isophthalate-bearing DOTA monoamide derivative has been synthesised and used to prepare a family of lanthanide complexes. Luminescence and NMR studies in solution show that the predominant form of the complexes in solution is a mono-capped square antiprism about the lanthanide centre, in which a...

Täydet tiedot

Bibliografiset tiedot
Päätekijät: Shiells, E, Natrajan, L, Sykes, D, Tropiano, M, Cooper, P, Kenwright, A, Faulkner, S
Aineistotyyppi: Journal article
Kieli:English
Julkaistu: 2011
Kuvaus
Yhteenveto:An isophthalate-bearing DOTA monoamide derivative has been synthesised and used to prepare a family of lanthanide complexes. Luminescence and NMR studies in solution show that the predominant form of the complexes in solution is a mono-capped square antiprism about the lanthanide centre, in which a solvent molecule occupies the ninth coordination site. The crystal structure of the terbium complex is presented and is in close agreement with the solution state data.