Intramolecular palladium-catalyzed direct arylation of alkenyl triflates.
A catalyst generated from Pd(OAc)2 and dppp is effective for the direct intramolecular arylation of alkenyl triflates. Conjugated alkene-arene-containing carbocycles are produced in good yield. The process tolerates a variety of aryl substituents as well a simple heteroaryl groups. Electron-deficien...
| Main Authors: | , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2007
|
| _version_ | 1797075706741522432 |
|---|---|
| author | Cruz, A Miller, N Willis, M |
| author_facet | Cruz, A Miller, N Willis, M |
| author_sort | Cruz, A |
| collection | OXFORD |
| description | A catalyst generated from Pd(OAc)2 and dppp is effective for the direct intramolecular arylation of alkenyl triflates. Conjugated alkene-arene-containing carbocycles are produced in good yield. The process tolerates a variety of aryl substituents as well a simple heteroaryl groups. Electron-deficient aryl rings deliver faster reactions. |
| first_indexed | 2024-03-06T23:54:04Z |
| format | Journal article |
| id | oxford-uuid:739b1149-bd0f-4b72-9557-ad4820d44177 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:54:04Z |
| publishDate | 2007 |
| record_format | dspace |
| spelling | oxford-uuid:739b1149-bd0f-4b72-9557-ad4820d441772022-03-26T19:57:25ZIntramolecular palladium-catalyzed direct arylation of alkenyl triflates.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:739b1149-bd0f-4b72-9557-ad4820d44177EnglishSymplectic Elements at Oxford2007Cruz, AMiller, NWillis, MA catalyst generated from Pd(OAc)2 and dppp is effective for the direct intramolecular arylation of alkenyl triflates. Conjugated alkene-arene-containing carbocycles are produced in good yield. The process tolerates a variety of aryl substituents as well a simple heteroaryl groups. Electron-deficient aryl rings deliver faster reactions. |
| spellingShingle | Cruz, A Miller, N Willis, M Intramolecular palladium-catalyzed direct arylation of alkenyl triflates. |
| title | Intramolecular palladium-catalyzed direct arylation of alkenyl triflates. |
| title_full | Intramolecular palladium-catalyzed direct arylation of alkenyl triflates. |
| title_fullStr | Intramolecular palladium-catalyzed direct arylation of alkenyl triflates. |
| title_full_unstemmed | Intramolecular palladium-catalyzed direct arylation of alkenyl triflates. |
| title_short | Intramolecular palladium-catalyzed direct arylation of alkenyl triflates. |
| title_sort | intramolecular palladium catalyzed direct arylation of alkenyl triflates |
| work_keys_str_mv | AT cruza intramolecularpalladiumcatalyzeddirectarylationofalkenyltriflates AT millern intramolecularpalladiumcatalyzeddirectarylationofalkenyltriflates AT willism intramolecularpalladiumcatalyzeddirectarylationofalkenyltriflates |