The electrochemical oxidation of cobalt tris(dithiocarbamates) and tris(diselenocarbamates) in acetonitrile; a combined spectroscopic and voltammetric study
The electrochemical oxidation of cobalt(III) dithiocarbamates and diselenocarbamates (CoL3) in acetonitrile + 0.1 M Bu4NPF6 is shown to occur via the mechanism: (E) CoL3↔[CoL3]+ + e-; (C2) 2[CoL3]+ → [Co2L5]+ + oxidized ligand; (C) [Co2L5]+ + 2CH3CN → CoL3 + [CoL2(CH3CN)2]+. A combination of electro...
| Hlavní autoři: | , , , , , , , |
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| Médium: | Journal article |
| Jazyk: | English |
| Vydáno: |
1998
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