Catalytic enantioselective intermolecular cycloadditions of a 2-diazo-3,6-diketoester-derived carbonyl ylide with alkyne and strained alkene dipolarophiles
Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition reactions of tert-butyl 2-diazo-3,6-dioxoheptanoate 7 with alkyne and strained alkene dipolarophiles to afford the corresponding cycloadducts with up to 92% ee are described. © 2003 Elsevier Science Ltd. All rights reserved.
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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2003
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| _version_ | 1826279260063531008 |
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| author | Hodgson, D Labande, A Glen, R Redgrave, A |
| author_facet | Hodgson, D Labande, A Glen, R Redgrave, A |
| author_sort | Hodgson, D |
| collection | OXFORD |
| description | Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition reactions of tert-butyl 2-diazo-3,6-dioxoheptanoate 7 with alkyne and strained alkene dipolarophiles to afford the corresponding cycloadducts with up to 92% ee are described. © 2003 Elsevier Science Ltd. All rights reserved. |
| first_indexed | 2024-03-06T23:56:05Z |
| format | Journal article |
| id | oxford-uuid:7445e752-baaf-46b7-843e-680c5423ee67 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:56:05Z |
| publishDate | 2003 |
| record_format | dspace |
| spelling | oxford-uuid:7445e752-baaf-46b7-843e-680c5423ee672022-03-26T20:01:38ZCatalytic enantioselective intermolecular cycloadditions of a 2-diazo-3,6-diketoester-derived carbonyl ylide with alkyne and strained alkene dipolarophilesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:7445e752-baaf-46b7-843e-680c5423ee67EnglishSymplectic Elements at Oxford2003Hodgson, DLabande, AGlen, RRedgrave, ACatalytic enantioselective tandem carbonyl ylide formation-cycloaddition reactions of tert-butyl 2-diazo-3,6-dioxoheptanoate 7 with alkyne and strained alkene dipolarophiles to afford the corresponding cycloadducts with up to 92% ee are described. © 2003 Elsevier Science Ltd. All rights reserved. |
| spellingShingle | Hodgson, D Labande, A Glen, R Redgrave, A Catalytic enantioselective intermolecular cycloadditions of a 2-diazo-3,6-diketoester-derived carbonyl ylide with alkyne and strained alkene dipolarophiles |
| title | Catalytic enantioselective intermolecular cycloadditions of a 2-diazo-3,6-diketoester-derived carbonyl ylide with alkyne and strained alkene dipolarophiles |
| title_full | Catalytic enantioselective intermolecular cycloadditions of a 2-diazo-3,6-diketoester-derived carbonyl ylide with alkyne and strained alkene dipolarophiles |
| title_fullStr | Catalytic enantioselective intermolecular cycloadditions of a 2-diazo-3,6-diketoester-derived carbonyl ylide with alkyne and strained alkene dipolarophiles |
| title_full_unstemmed | Catalytic enantioselective intermolecular cycloadditions of a 2-diazo-3,6-diketoester-derived carbonyl ylide with alkyne and strained alkene dipolarophiles |
| title_short | Catalytic enantioselective intermolecular cycloadditions of a 2-diazo-3,6-diketoester-derived carbonyl ylide with alkyne and strained alkene dipolarophiles |
| title_sort | catalytic enantioselective intermolecular cycloadditions of a 2 diazo 3 6 diketoester derived carbonyl ylide with alkyne and strained alkene dipolarophiles |
| work_keys_str_mv | AT hodgsond catalyticenantioselectiveintermolecularcycloadditionsofa2diazo36diketoesterderivedcarbonylylidewithalkyneandstrainedalkenedipolarophiles AT labandea catalyticenantioselectiveintermolecularcycloadditionsofa2diazo36diketoesterderivedcarbonylylidewithalkyneandstrainedalkenedipolarophiles AT glenr catalyticenantioselectiveintermolecularcycloadditionsofa2diazo36diketoesterderivedcarbonylylidewithalkyneandstrainedalkenedipolarophiles AT redgravea catalyticenantioselectiveintermolecularcycloadditionsofa2diazo36diketoesterderivedcarbonylylidewithalkyneandstrainedalkenedipolarophiles |