Catalytic enantioselective intermolecular cycloadditions of a 2-diazo-3,6-diketoester-derived carbonyl ylide with alkyne and strained alkene dipolarophiles

Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition reactions of tert-butyl 2-diazo-3,6-dioxoheptanoate 7 with alkyne and strained alkene dipolarophiles to afford the corresponding cycloadducts with up to 92% ee are described. © 2003 Elsevier Science Ltd. All rights reserved.

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: Hodgson, D, Labande, A, Glen, R, Redgrave, A
Формат: Journal article
Хэл сонгох:English
Хэвлэсэн: 2003