Palladium catalysed allene carbocyclisation

Palladium catalysed allene carbocyclisation

<p>In this thesis, firstly, a Pd-catalysed diastereoselective carbocyclisation of allenes with aryl halides or vinyl iodides was designed and developed to form arylative or vinylative spirolactam compounds. High yields and diastereoselectivities were obtained in the presence of Pd<sub>2&...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолч:	Li, M
Бусад зохиолчид:	Dixon, D
Формат:	Дипломын ажил
Хэл сонгох:	English
Хэвлэсэн:	2010
Нөхцлүүд:	Organic chemistry Organic synthesis

Ижил төстэй зүйлс

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Palladium- and copper-catalysed heterocycle synthesis
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Synthesis of heterocycles via palladium-catalysed direct arylation
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Palladium-catalysed cyclisations of bromoenynamides in the synthesis and applications of amidodienes
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Novel palladium-catalysed routes to aromatic heterocycles
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Palladium-catalysed cascade cyclisation of alkynyl silanes and studies towards rubriflordilactone A
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One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation
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Synthesis of mono- and bicyclic azacycles via palladium- and ruthenium-catalysed enynamide cycloisomerisation
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Palladium-catalysed heterocycle synthesis
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Synthesis of polyhydroxylated alkaloids via allene cyclisation
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Synthesis of piperidine natural products by allenic cyclisation
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Aziridinations of tethered allenes
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Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
-н: Ylioja, P
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Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions
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Tandem catalytic processes involving Rhodium-catalysed intermolecular hydroacylation
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Palladium(II)-catalyzed alkenyl C-H bond functionalization
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Transition metal catalysed C-C bond formation via C-H functionalisation
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Palladium mediated allylic fluorination
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Synthesis and elaboration of heterocycles via palladium-catalyzed C-H functionalization
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Part I. Palladium-catalysed C-glycosylations. Part II. Synthesis of indolizines via intramolecular C-N bond formation
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Gold-catalysed functionalisations of yndiamides
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Part I: Iron (III)-catalyzed reactions of benzylic analogs with organosilanes & Conia-ene cyclization. Part II: Palladium (II)-catalyzed C-H functionalizations using mono-phosphoric acid directing group
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Part 1: Synthesis of vinyl sulfones via palladium-catalyzed sulfonylation of olefins. Part 2: Trienes : Synthesis via C-H Functionalization and as precursors to complex molecules.
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Part I Indium-mediated THP ring formation and transformation of halo group into hydroxyl group Part II Palladium-catalyzed direct arylation of cyclic enamides with arylmetallic reagents
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Applications of rhodium-catalysed hydroacylation in heterocycle synthesis
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New applications of rhodium-catalysed hydroacylation
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Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions
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Linear allylic halides in metal-catalysed asymmetric substitutions
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Iridium-catalysed hydrosilylation of carbonyl derivatives: design and applications
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The iridium-catalysed alkylation of aromatic ketones via hydrogen borrowing
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New asymmetric metal-catalysed addition processes for amine synthesis
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Synthesis of (−)-deoxynupharidine by allenic hydroxylamine cyclisation
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Rhodium-catalysed regio- and enantioselective Suzuki-Miyaura cross-coupling reactions
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The development and applications of the Lewis acid-mediated osmium-catalysed oxidative cyclisation
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Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
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Enantioselective Steglich rearrangement catalysed by chiral guanidinium ion pairs
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New reactivity and selectivity in rhodium-catalysed hydroacylation
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Homologation of aryl ketones to long-chain ketones and aldehydes via C–C bond cleavage
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Fluorinated tetrapodal anion transporters
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