Synthesis of cyclic alkenylsiloxanes by semihydrogenation: A stereospecific route to (Z)-alkenyl polyenes

Synthesis of cyclic alkenylsiloxanes by semihydrogenation: A stereospecific route to (Z)-alkenyl polyenes

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Cyclic alkenylsiloxanes were synthesized by semihydrogenation of alkynylsilanes - a reaction previously plagued by poor stereoselectivity. The silanes, which can be synthesized on multigram scale, undergo Hiyama-Denmark coupling to give (Z)-alkenyl polyene motifs found in bioactive natural products....

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Bibliografiske detaljer
Main Authors:	Elbert, B, Lim, D, Gudmundsson, H, O'Hanlon, J, Anderson, E
Format:	Journal article
Sprog:	English
Udgivet:	Wiley 2014

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