The first example of the two‐electron reduction of a phosphaalkyne – synthesis and structural characterisation of the diuranium(IV) pentalene complex [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3‐1,4)2})2(μ‐η2:η1‐tBuCP)]
The facile two‐electron reduction of the phosphaalkyne tBuC≡P by the UIII cyclopentadienyl–pentalene mixed‐sandwich complex [U(η5‐C5Me5){η8‐C8H4(SiiPr3)2}] is reported. A single‐crystal X‐ray structural analysis of the diuranium(IV) product [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3)2})2(μ‐tBuCP)] shows that it c...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
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Wiley
2013
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| _version_ | 1824458699129749504 |
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| author | Tsoureas, N Kilpatrick, A Summerscales, OT Nixon, JF Cloke, FGN Hitchcock, PB |
| author_facet | Tsoureas, N Kilpatrick, A Summerscales, OT Nixon, JF Cloke, FGN Hitchcock, PB |
| author_sort | Tsoureas, N |
| collection | OXFORD |
| description | The facile two‐electron reduction of the phosphaalkyne tBuC≡P by the UIII cyclopentadienyl–pentalene mixed‐sandwich complex [U(η5‐C5Me5){η8‐C8H4(SiiPr3)2}] is reported. A single‐crystal X‐ray structural analysis of the diuranium(IV) product [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3)2})2(μ‐tBuCP)] shows that it contains a slightly unsymmetrical, bridging μ‐η2:η1‐ligated phosphaalkene dianion. |
| first_indexed | 2025-02-19T04:30:02Z |
| format | Journal article |
| id | oxford-uuid:74a5ea8d-310d-4567-8801-f2bdf39a69b4 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2025-02-19T04:30:02Z |
| publishDate | 2013 |
| publisher | Wiley |
| record_format | dspace |
| spelling | oxford-uuid:74a5ea8d-310d-4567-8801-f2bdf39a69b42024-12-17T11:17:42ZThe first example of the two‐electron reduction of a phosphaalkyne – synthesis and structural characterisation of the diuranium(IV) pentalene complex [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3‐1,4)2})2(μ‐η2:η1‐tBuCP)]Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:74a5ea8d-310d-4567-8801-f2bdf39a69b4EnglishSymplectic Elements at OxfordWiley2013Tsoureas, NKilpatrick, ASummerscales, OTNixon, JFCloke, FGNHitchcock, PBThe facile two‐electron reduction of the phosphaalkyne tBuC≡P by the UIII cyclopentadienyl–pentalene mixed‐sandwich complex [U(η5‐C5Me5){η8‐C8H4(SiiPr3)2}] is reported. A single‐crystal X‐ray structural analysis of the diuranium(IV) product [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3)2})2(μ‐tBuCP)] shows that it contains a slightly unsymmetrical, bridging μ‐η2:η1‐ligated phosphaalkene dianion. |
| spellingShingle | Tsoureas, N Kilpatrick, A Summerscales, OT Nixon, JF Cloke, FGN Hitchcock, PB The first example of the two‐electron reduction of a phosphaalkyne – synthesis and structural characterisation of the diuranium(IV) pentalene complex [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3‐1,4)2})2(μ‐η2:η1‐tBuCP)] |
| title | The first example of the two‐electron reduction of a phosphaalkyne – synthesis and structural characterisation of the diuranium(IV) pentalene complex [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3‐1,4)2})2(μ‐η2:η1‐tBuCP)] |
| title_full | The first example of the two‐electron reduction of a phosphaalkyne – synthesis and structural characterisation of the diuranium(IV) pentalene complex [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3‐1,4)2})2(μ‐η2:η1‐tBuCP)] |
| title_fullStr | The first example of the two‐electron reduction of a phosphaalkyne – synthesis and structural characterisation of the diuranium(IV) pentalene complex [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3‐1,4)2})2(μ‐η2:η1‐tBuCP)] |
| title_full_unstemmed | The first example of the two‐electron reduction of a phosphaalkyne – synthesis and structural characterisation of the diuranium(IV) pentalene complex [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3‐1,4)2})2(μ‐η2:η1‐tBuCP)] |
| title_short | The first example of the two‐electron reduction of a phosphaalkyne – synthesis and structural characterisation of the diuranium(IV) pentalene complex [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3‐1,4)2})2(μ‐η2:η1‐tBuCP)] |
| title_sort | first example of the two electron reduction of a phosphaalkyne synthesis and structural characterisation of the diuranium iv pentalene complex u η5 c5me5 η8 c8h4 siipr3 1 4 2 2 μ η2 η1 tbucp |
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