Reversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2.
The hydroxyhydrido salt [Rh(6)(P(i)Pr(3))(6)H(11)(OH)][BArF(4)](2) results from the addition of water to [Rh(6)(P(i)Pr(3))(6)H(12)][BArF(4)](2). This reaction is reversible, and the addition of dihydrogen to [Rh(6)(P(i)Pr(3))(6)H(11)(OH)][BArF(4)](2) results in the elimination of water and the regen...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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2008
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| _version_ | 1797076065069301760 |
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| author | Douglas, T Brayshaw, S Raithby, P Weller, A |
| author_facet | Douglas, T Brayshaw, S Raithby, P Weller, A |
| author_sort | Douglas, T |
| collection | OXFORD |
| description | The hydroxyhydrido salt [Rh(6)(P(i)Pr(3))(6)H(11)(OH)][BArF(4)](2) results from the addition of water to [Rh(6)(P(i)Pr(3))(6)H(12)][BArF(4)](2). This reaction is reversible, and the addition of dihydrogen to [Rh(6)(P(i)Pr(3))(6)H(11)(OH)][BArF(4)](2) results in the elimination of water and the regeneration of the hydride cluster. |
| first_indexed | 2024-03-06T23:58:55Z |
| format | Journal article |
| id | oxford-uuid:753dcbf7-38eb-441f-82cc-0d4ef630fca1 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T23:58:55Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:753dcbf7-38eb-441f-82cc-0d4ef630fca12022-03-26T20:08:05ZReversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:753dcbf7-38eb-441f-82cc-0d4ef630fca1EnglishSymplectic Elements at Oxford2008Douglas, TBrayshaw, SRaithby, PWeller, AThe hydroxyhydrido salt [Rh(6)(P(i)Pr(3))(6)H(11)(OH)][BArF(4)](2) results from the addition of water to [Rh(6)(P(i)Pr(3))(6)H(12)][BArF(4)](2). This reaction is reversible, and the addition of dihydrogen to [Rh(6)(P(i)Pr(3))(6)H(11)(OH)][BArF(4)](2) results in the elimination of water and the regeneration of the hydride cluster. |
| spellingShingle | Douglas, T Brayshaw, S Raithby, P Weller, A Reversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2. |
| title | Reversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2. |
| title_full | Reversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2. |
| title_fullStr | Reversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2. |
| title_full_unstemmed | Reversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2. |
| title_short | Reversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2. |
| title_sort | reversible addition of water to the high hydride content cluster rh6 pipr3 6h12 barf4 2 synthesis and structure of rh6pipr3 6h11 oh barf4 2 |
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